597910
(4-氯苯基)三乙氧基硅烷
97%
别名:
氯代苯基三乙氧基硅烷
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关于此项目
线性分子式:
ClC6H4Si(OC2H5)3
化学文摘社编号:
分子量:
274.82
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
EC Number:
244-533-9
MDL number:
产品名称
(4-氯苯基)三乙氧基硅烷, 97%
InChI
1S/C12H19ClO3Si/c1-4-14-17(15-5-2,16-6-3)12-9-7-11(13)8-10-12/h7-10H,4-6H2,1-3H3
InChI key
AFILDYMJSTXBAR-UHFFFAOYSA-N
SMILES string
CCO[Si](OCC)(OCC)c1ccc(Cl)cc1
assay
97%
refractive index
n20/D 1.474 (lit.)
bp
82-84 °C/0.07 mmHg (lit.)
density
1.069 g/mL at 25 °C (lit.)
functional group
chloro
Quality Level
Application
(4-Chlorophenyl)triethoxysilane can be used:
- To facilitate the connection between dipolar mixed monolayers and zinc oxide in photovoltaic devices.
- As a substrate in the Ni-catalyzed decarboxylative coupling with alkynyl carboxylic acids to yield substituted diarylalkynes.
- As a substrate in the Hiyama cross-coupling reactions with 3-iodoazetidines to yield substituted 3-arylazetidines.
- As an intermediate in the synthesis of tripod-shaped oligo(p-phenylene)s, which are used in the surface immobilization of gold and CdS quantum dots for sensor applications.
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
>230.0 °F - closed cup
flash_point_c
> 110 °C - closed cup
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
Palladium-Catalyzed Hiyama Cross-Couplings of Arylsilanes with 3-Iodoazetidine: Synthesis of 3-Arylazetidines
Liu Z, et al.
The Journal of Organic Chemistry, 84(19), 12358-12365 (2019)
Tuning zinc oxide/organic energy level alignment using mixed triethoxysilane monolayers
Brenner TM, et al.
Journal of Material Chemistry C, 1(37), 5935-5943 (2013)
Synthesis of azobenzene substituted tripod-shaped bi (p-phenylene) s. Adsorption on gold and CdS quantum-dots surfaces
Hierrezuelo J, et al.
Tetrahedron, 69(16), 3465-3474 (2013)
Nickel-catalyzed Hiyama-type decarboxylative coupling of propiolic acids and organosilanes
Edwin Raja GC, et al.
The Journal of Organic Chemistry, 81(12), 5244-5249 (2016)
Denmark, S. E.; Ober, M. H.
Aldrichimica Acta, 36, 75-75 (2003)
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