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Merck
CN

61030

三氟乙酸

≥99% (alkalimetric)

别名:

TFA

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线性分子式:
CF3COOH
化学文摘社编号:
分子量:
114.02
EC Number:
200-929-3
UNSPSC Code:
12352106
MDL number:
Beilstein/REAXYS Number:
742035
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InChI

1S/C2HF3O2/c3-2(4,5)1(6)7/h(H,6,7)

InChI key

DTQVDTLACAAQTR-UHFFFAOYSA-N

SMILES string

OC(C(F)(F)F)=O

vapor density

3.9 (vs air)

vapor pressure

97.5 mmHg ( 20 °C)

assay

≥99% (alkalimetric)

color

APHA: ≤25

refractive index

n20/D 1.3 (lit.)

mp

−15.4 °C (lit.)

density

1.489 g/mL at 20 °C (lit.)

suitability

clear, colorless for appearance (liquid), in accordance for identity (IR)

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Legal Information

Riedel-de Haën is a registered trademark of Honeywell Specialty Chemicals Seelze GmbH.

pictograms

CorrosionExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1A

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 2

flash_point_f

>212.0 °F - Pensky-Martens closed cup

flash_point_c

> 100 °C - Pensky-Martens closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

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分析证书(COA)

Lot/Batch Number

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Alan Chuan-Ying Lai et al.
Rapid communications in mass spectrometry : RCM, 26(18), 2186-2194 (2012-08-14)
Despite advances in mass spectrometry (MS)-based identification, effective phosphopeptide enrichment is a prerequisite towards comprehensive phosphoproteomic analysis. Based on the different binding affinities and coordination geometries of the Ti(4+) and Fe(3+) ions with the phosphate group, we report a complementary
Xuan Ye et al.
The Journal of organic chemistry, 78(5), 2083-2090 (2012-11-20)
The stereochemical course of the amidopalladation of alkenes has important implications for the development of enantioselective Pd-catalyzed "Wacker-type" oxidative amidation of alkenes. We have recently shown that the addition of base (Na2CO3) can alter the stereochemical course of amidopalladation in
S V Stovbun et al.
Bulletin of experimental biology and medicine, 153(6), 843-845 (2012-11-01)
The dynamics of string growth was studied in model homochiral solutions of biomimetics, trifluoroacetylated amino alcohols (TFAAA) in heptane, water, and inverted heptane-water emulsion. In heptane and water, a thick (~1 μ in diameter) string had a crown of thin
Pasquale Palladino et al.
Organic letters, 14(24), 6346-6349 (2012-12-06)
A novel method for cleaving from resin and removing acid-labile protecting groups for the Fmoc solid-phase peptide synthesis is described. 0.1 N HCl in hexafluoroisopropanol or trifluoroethanol cleanly and rapidly removes the tert-butyl ester and ether, Boc, trityl, and Pbf
Yukiko Enomoto-Rogers et al.
Carbohydrate polymers, 92(2), 1827-1834 (2013-02-13)
Fully substituted glucomannan triacetate (GMTAc) (degree of substitution (DS)=3.0) was prepared from konjac glucomannan (KGM) treated with acetic acid and trifluoroacetic anhydride (TFAA). The peaks in the (1)H- and (13)C NMR spectra of GMTAc were assigned in detail based on

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