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关于此项目
经验公式(希尔记法):
C10H10O3
化学文摘社编号:
分子量:
178.18
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
97%
InChI
1S/C10H10O3/c1-2-8-12-10(11)13-9-6-4-3-5-7-9/h2-7H,1,8H2
SMILES string
C=CCOC(=O)Oc1ccccc1
InChI key
ORUWSEKEVGOAQR-UHFFFAOYSA-N
assay
97%
refractive index
n20/D 1.4990 (lit.)
bp
67-70 °C/0.3 mmHg (lit.)
density
1.096 g/mL at 25 °C (lit.)
functional group
carbonate, phenoxy
General description
Allyl phenyl carbonate can be obtained via by reacting phenyl chloroformate and allyl alcohol in presence of pyridine.
Application
Allyl phenyl carbonate can react with (2-alkynyl)phenylisocyanate, catalyzed P(0)/Cu(I) system to give the corresponding indole.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Sens. 1
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
>230.0 °F
flash_point_c
> 110 °C
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
"A New Pd0?CuI Bimetallic Catalyst for the Synthesis of Indoles from Isocyanates and Allyl Carbonates"
Kamijo S and Yamamoto Y
Angewandte Chemie (Weinheim an der Bergstrasse, Germany), 114(17), 3364-3367 (2002)
?Selective synthesis of carbamate protected polyamines using alkyl phenyl carbonates"
Pittelkow M, et al.
Synthesis, 2002(15), 2195- 2202 (2002)
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