634816
4-（甲硫基）溴苄
97%
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关于此项目
经验公式（希尔记法）:
C8H9BrS
化学文摘社编号:
分子量:
217.13
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
97%
Form:
solid
InChI
1S/C8H9BrS/c1-10-8-4-2-7(6-9)3-5-8/h2-5H,6H2,1H3
SMILES string
CSc1ccc(CBr)cc1
InChI key
QDLKMRTVELBKFE-UHFFFAOYSA-N
assay
97%
form
solid
mp
43-47 °C (lit.)
functional group
bromo, thioether
Application
4-(Methylthio)benzyl bromide can undergo self-catalyzed oxidation in the presence of hydrogen peroxide to form the corresponding sulfoxide.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Skin Corr. 1B - Skin Sens. 1
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
>230.0 °F - closed cup
flash_point_c
> 110 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
"Self-Catalyzed Oxidation of Sulfides with Hydrogen Peroxide: A Green and Practical Process for the Synthesis of Sulfoxides"
Shi F, et al.
Advanced Synthesis & Catalysis, 349(16), 2425-2430 (2007)
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