637998
乙烯硼酐吡啶络合物
95%
别名:
2,4,6-三乙烯基环三硼烷吡啶配合物, 三乙烯基-硼氧杂环丁烷吡啶配合物
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关于此项目
经验公式（希尔记法）:
C6H9B3O3 · C5H5N
化学文摘社编号:
分子量:
240.67
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22
方案
95%
表单
solid
储存温度
−20°C
SMILES字符串
c1ccncc1.C=Cb2ob(C=C)ob(C=C)o2
InChI
1S/C6H9B3O3.C5H5N/c1-4-7-10-8(5-2)12-9(6-3)11-7;1-2-4-6-5-3-1/h4-6H,1-3H2;1-5H
InChI key
YLHJACXHRQQNQR-UHFFFAOYSA-N
应用
作为试剂用于以下反应
用于制备以下化合物的试剂
- Suzuki-Miyaura交叉偶联
- 通过钯催化的碳氨化反应进行立体选择性合成
- 烷基连接的2-氨基-6-乙烯基嘌呤（AVP）与RNA中的胞嘧啶碱基的交联剂
- Kaiser肟树脂衍生的钯环作为在水相介质中Suzuki-Miyaura交叉偶联反应的可回收聚合物预催化剂
- 二萘酚衍生物的磷酸酯和磺酰基酯通过钯催化的乙烯醚醇解的反应动力学解析
- 通过使用氢化铑催化将N-烯丙基氮丙啶立体选择性异构化为Z-烯胺
- 通过钯/手性二胺配体催化的醇解反应对轴向手性联芳基衍生物的动力学解析
- 过渡金属催化的氮丙啶的烯基化、环加成和热重排反应
- 分子内Heck反应策略用于合成功能化的四氢蒽
用于制备以下化合物的试剂
- BACE-1抑制剂和环状砜羟乙胺的SAR
- 扭曲的螺旋戊烷
- 血管水肿治疗中的小分子缓激肽B2受体拮抗剂
- 烯醇醚
- 苯乙烯基环丁酮
警示用语：
Warning
危险声明
预防措施声明
危险分类
Eye Irrit. 2
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
176.0 °F - closed cup
闪点(°C)
80 °C - closed cup
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
Kaiser oxime resin-derived palladacycle: A recoverable polymeric precatalyst in Suzuki-Miyaura reactions in aqueous media
Alacid, E.; Najera, C.
Journal of Organometallic Chemistry, 694, 1658-1665 (2009)
Shadi Dalili et al.
Organic letters, 7(6), 1161-1164 (2005-03-12)
[reaction: see text] Straightforward methods for palladium-catalyzed alkenylation of aziridines with alkenyl halides and copper-catalyzed alkenylation of aziridines with alkenyl boronic acids have been developed. This methodology offers attractive alternatives to the known methods requiring activated alkenyl halides and acetylenes.
Heinrich Rueeger et al.
Bioorganic & medicinal chemistry letters, 21(7), 1942-1947 (2011-03-11)
This Letter describes the de novo design of non-peptidic hydroxyethylamine (HEA) inhibitors of BACE-1 by elimination of P-gp contributing amide attachments. The predicted binding mode of the novel cyclic sulfone HEA core template was confirmed in a X-ray co-crystal structure.
Kinetic resolution of axially chiral 2,2'-dihydroxy-1,1'-biaryls by palladium-catalyzed alcoholysis.
Hiroshi Aoyama et al.
Journal of the American Chemical Society, 127(30), 10474-10475 (2005-07-28)
Palladium-diamine complexes catalyzed kinetic resolution of axially chiral 2,2'-dihydroxy-1,1'-biaryls by alcoholysis of vinyl ethers. The reaction proceeded with high selectivity for various kinds of biaryls. This process is applicable to not only binaphthols but also biphenols, which have been considered
Suzuki-Miyaura cross-coupling: preparation of 2'-vinylacetanilide
Cottineau, B.; Kessler, A.; O'Shea, D. F.
Organic Syntheses, 83 (2006)
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