form
solid
crosslinking
1 % cross-linked with divinylbenzene
extent of labeling
1.0 mmol/g loading
particle size
50-100 mesh
storage temp.
2-8°C
Application
重氮基转移试剂。
Kazuo Yamazaki et al.
Chemical communications (Cambridge, England), (3), 210-211 (2002-07-18)
Rh(II)-catalyzed N-H insertion reaction of immobilized alpha-diazophosphonoacetate with 2-haloanilines followed by Horner-Emmons reaction gave immobilized enaminoesters, which were efficiently cyclized to indoles via intramolecular palladium catalyzed reaction on a polymer support.
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