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经验公式(希尔记法):
C10H20O2Si
化学文摘社编号:
分子量:
200.35
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
InChI
1S/C10H20O2Si/c1-7-10(9(2)8-11-3)12-13(4,5)6/h7-8H,1-6H3/b9-8+,10-7-
SMILES string
CO\C=C(C)\C(O[Si](C)(C)C)=C\C
InChI key
SSGAQVOLXCOJGN-AZRUORMVSA-N
refractive index
n20/D 1.4650 (lit.)
bp
65 °C/6 mmHg (lit.)
density
0.899 g/mL at 25 °C (lit.)
functional group
ether
storage temp.
2-8°C
Application
Danishefsky diene used as a reactant for:
Preparation of migrastatin analog as cell migration inhibitor for treatment of tumor metastasis
Preparation of dihydropyridinones by chlorosilane-promoted aza-Diels-Alder addition
Synthesis on non-proteinogenic amino esters via stereoselective Lewis acid-catalyzed aza-Diels-Alder cycloaddition with conjugated (cyclo)dienes
Preparation of migrastatin analog as cell migration inhibitor for treatment of tumor metastasis
Preparation of dihydropyridinones by chlorosilane-promoted aza-Diels-Alder addition
Synthesis on non-proteinogenic amino esters via stereoselective Lewis acid-catalyzed aza-Diels-Alder cycloaddition with conjugated (cyclo)dienes
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