643181
钯
extent of labeling: 5 wt. % loading (dry basis), matrix activated carbon, wet support, Degussa type E105CA/W
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关于此项目
线性分子式:
Pd
化学文摘社编号:
分子量:
106.42
UNSPSC Code:
12141733
PubChem Substance ID:
MDL number:
InChI
1S/Pd
SMILES string
[Pd]
InChI key
KDLHZDBZIXYQEI-UHFFFAOYSA-N
reaction suitability
core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
extent of labeling
5 wt. % loading (dry basis)
resistivity
9.96 μΩ-cm, 20°C
matrix
activated carbon, wet support
bp
2970 °C (lit.)
mp
1554 °C (lit.)
density
12.02 g/cm3 (lit.)
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Application
用作氢化烯烃、炔烃、酮、腈、亚胺、叠氮化物、硝基、苯型和杂环芳族化合物的催化剂;用于环丙烷、苄基衍生物、环氧化物、肼和卤化物的氢解;用于使芳烃脱氢和使醛变性。
用作碳-碳偶联反应（Heck和Suzuki）的非均相催化剂
通过在水中将苯基硼酸与4-氯-苯乙酮进行Suzuki-Miyaura交联，它可以与活性炭上的无配体钯一起用于制备1-联苯-4-基-乙酮。
存储类别
13 - Non Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Suzuki-Miyaura cross-coupling of aryl chlorides in water using ligandless palladium on activated carbon.
Lysen M and Kohler K.
Synlett, 2005(11), 1671-1674 (2005)
Meifang Zheng et al.
Organic letters, 15(8), 1838-1841 (2013-04-02)
Palladium-catalyzed oxidative difunctionalization of enol ethers with 1,3-dicarbonyl compounds to construct trisubstituted furans in one step under mild conditions is described. The reaction is thought to proceed through a C-C bond formation along with a C-O bond closing the ring
V Volarevic et al.
Journal of B.U.ON. : official journal of the Balkan Union of Oncology, 18(1), 131-137 (2013-04-25)
As novel therapeutic agents relevant to colon cancer therapy are explored continuously, we tested 4 R2edda-type ligand precursors O,O'-dialkyl esters of (S,S)-ethylenediamine-N,N'-di-2-(4-methyl)pentanoic acid (L1.2HCl-L4.2HCl) and corresponding palladium(II) and platinum(II) complexes against the human colon cancer cell lines CaCo-2, SW480 and
Ling Li et al.
Nature chemistry, 5(7), 607-612 (2013-06-22)
The development of transition metal-catalysed cross-coupling reactions has greatly influenced the manner in which the synthesis of complex organic molecules is approached. A wide variety of methods are now available for the formation of C(sp(2))-C(sp(2)) bonds, and more recent work
Daniel Smykowski et al.
Journal of molecular graphics & modelling, 41, 89-96 (2013-03-21)
This study is the analysis of the adsorption process of the CO2 molecule on the cationic sites of the DOH zeolite. Based on the DFT method, we have been able to identify several adsorption sites containing extra-framework cations and evaluate
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