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643181

钯

extent of labeling: 5 wt. % loading (dry basis), matrix activated carbon, wet support, Degussa type E105CA/W

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关于此项目

线性分子式:
Pd
化学文摘社编号:
7440-05-3
分子量:
106.42
UNSPSC Code:
12141733
PubChem Substance ID:
24883258
MDL number:
MFCD00011167
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reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

extent of labeling

5 wt. % loading (dry basis)

resistivity

9.96 μΩ-cm, 20°C

matrix

activated carbon, wet support

bp

2970 °C (lit.)

mp

1554 °C (lit.)

density

12.02 g/cm3 (lit.)

SMILES string

[Pd]

InChI

1S/Pd

InChI key

KDLHZDBZIXYQEI-UHFFFAOYSA-N

Application

通过在水中将苯基硼酸与4-氯-苯乙酮进行Suzuki-Miyaura交联，它可以与活性炭上的无配体钯一起用于制备1-联苯-4-基-乙酮。
用作氢化烯烃、炔烃、酮、腈、亚胺、叠氮化物、硝基、苯型和杂环芳族化合物的催化剂;用于环丙烷、苄基衍生物、环氧化物、肼和卤化物的氢解;用于使芳烃脱氢和使醛变性。
用作碳-碳偶联反应（Heck和Suzuki）的非均相催化剂

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存储类别

13 - Non Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKBS2758V
MKBQ4979V
MKBJ9424V
MKBD6757
MKBC1420

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Suzuki-Miyaura cross-coupling of aryl chlorides in water using ligandless palladium on activated carbon.
Lysen M and Kohler K.
Synlett, 2005(11), 1671-1674 (2005)
V Volarevic et al.
Journal of B.U.ON. : official journal of the Balkan Union of Oncology, 18(1), 131-137 (2013-04-25)
As novel therapeutic agents relevant to colon cancer therapy are explored continuously, we tested 4 R2edda-type ligand precursors O,O'-dialkyl esters of (S,S)-ethylenediamine-N,N'-di-2-(4-methyl)pentanoic acid (L1.2HCl-L4.2HCl) and corresponding palladium(II) and platinum(II) complexes against the human colon cancer cell lines CaCo-2, SW480 and
Ling Li et al.
Nature chemistry, 5(7), 607-612 (2013-06-22)
The development of transition metal-catalysed cross-coupling reactions has greatly influenced the manner in which the synthesis of complex organic molecules is approached. A wide variety of methods are now available for the formation of C(sp(2))-C(sp(2)) bonds, and more recent work
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全球贸易项目编号

货号GTIN
643181-10G04061833548707
643181-50G04061833548714