643181
钯
extent of labeling: 5 wt. % loading (dry basis), matrix activated carbon, wet support, Degussa type E105CA/W
反应适用性
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
标记范围
5 wt. % loading (dry basis)
电阻率
9.96 μΩ-cm, 20°C
基质
activated carbon, wet support
沸点
2970 °C (lit.)
mp
1554 °C (lit.)
密度
12.02 g/cm3 (lit.)
SMILES字符串
[Pd]
InChI
1S/Pd
InChI key
KDLHZDBZIXYQEI-UHFFFAOYSA-N
正在寻找类似产品? 访问 产品对比指南
应用
用作氢化烯烃、炔烃、酮、腈、亚胺、叠氮化物、硝基、苯型和杂环芳族化合物的催化剂;用于环丙烷、苄基衍生物、环氧化物、肼和卤化物的氢解;用于使芳烃脱氢和使醛变性。
用作碳-碳偶联反应（Heck和Suzuki）的非均相催化剂
通过在水中将苯基硼酸与4-氯-苯乙酮进行Suzuki-Miyaura交联，它可以与活性炭上的无配体钯一起用于制备1-联苯-4-基-乙酮。
储存分类代码
13 - Non Combustible Solids
WGK
WGK 2
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Suzuki-Miyaura cross-coupling of aryl chlorides in water using ligandless palladium on activated carbon.
Lysen M and Kohler K.
Synlett, 2005(11), 1671-1674 (2005)
Meifang Zheng et al.
Organic letters, 15(8), 1838-1841 (2013-04-02)
Palladium-catalyzed oxidative difunctionalization of enol ethers with 1,3-dicarbonyl compounds to construct trisubstituted furans in one step under mild conditions is described. The reaction is thought to proceed through a C-C bond formation along with a C-O bond closing the ring
Bin Kim et al.
Journal of nanoscience and nanotechnology, 13(1), 517-522 (2013-05-08)
In order to form flexible printed circuits through inkjet printing technique, the Pd(ll) catalyst ink was printed on the surface of polyimide film modified with KOH solution and then reduced with NaBH4 solution to extract the Pd(O) catalyst nuclei. The
On the role of surface diffusion in determining the shape or morphology of noble-metal nanocrystals.
Xiaohu Xia et al.
Proceedings of the National Academy of Sciences of the United States of America, 110(17), 6669-6673 (2013-04-10)
Controlling the shape or morphology of metal nanocrystals is central to the realization of their many applications in catalysis, plasmonics, and electronics. In one of the approaches, the metal nanocrystals are grown from seeds of certain crystallinity through the addition
V Volarevic et al.
Journal of B.U.ON. : official journal of the Balkan Union of Oncology, 18(1), 131-137 (2013-04-25)
As novel therapeutic agents relevant to colon cancer therapy are explored continuously, we tested 4 R2edda-type ligand precursors O,O'-dialkyl esters of (S,S)-ethylenediamine-N,N'-di-2-(4-methyl)pentanoic acid (L1.2HCl-L4.2HCl) and corresponding palladium(II) and platinum(II) complexes against the human colon cancer cell lines CaCo-2, SW480 and
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持