644145
(1S,2R)-1-[(3,5-二叔丁基-2-羟基亚苄基)氨基]-2-茚醇
97%
别名:
(1S,2R)-1-((2-羟基-3,5-二叔丁基亚苄基)氨基)茚满-2-醇
方案
97%
表单
solid
mp
128-131 °C
官能团
hydroxyl
imine
SMILES字符串
CC(C)(C)c1cc(\C=N\[C@@H]2[C@H](O)Cc3ccccc23)c(O)c(c1)C(C)(C)C
InChI
1S/C24H31NO2/c1-23(2,3)17-11-16(22(27)19(13-17)24(4,5)6)14-25-21-18-10-8-7-9-15(18)12-20(21)26/h7-11,13-14,20-21,26-27H,12H2,1-6H3/b25-14+/t20-,21+/m1/s1
InChI key
MMNHXVSQIRTBOZ-FOYRYCBESA-N
应用
(1S,2R)-1-[(3,5-Di-tert-butyl-2-hydroxybenzylidene)amino]-2-indanol can be used as a ligand to prepare Schiff-base chromium(III) complex, which is used as a catalyst in the synthesis of:
- Poly(cyclohexene carbonate) by coupling of CO2 and cyclohexene oxide.
- β-hydroxyenol ethers by asymmetric hetero-ene reaction between aryl aldehydes and 2-methoxypropene.
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Rebecca T Ruck et al.
Journal of the American Chemical Society, 124(12), 2882-2883 (2002-03-21)
Tridentate Schiff base chromium(III) complex 1 catalyzes the asymmetric hetero-ene reaction between aryl aldehydes and either 2-methoxypropene or 2-trimethylsilyloxypropene to provide a series of beta-hydroxyenol ether products in high yields and enantioselectivities. X-ray crystallographic analysis of a closely related chromium
COPOLYMERIZATION OF CO2 AND EPOXIDES CATALYZED BY A SCHIFF-BASE CHROMIUM(III) COMPLEX (2019)
Pellotier, B. et al.
Synlett, 1055-1055 (2002)
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持