644145
(1S,2R)-1-[(3,5-二叔丁基-2-羟基亚苄基)氨基]-2-茚醇
97%
别名:
(1S,2R)-1-((2-羟基-3,5-二叔丁基亚苄基)氨基)茚满-2-醇
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关于此项目
经验公式（希尔记法）:
C24H31NO2
化学文摘社编号:
分子量:
365.51
UNSPSC Code:
12352116
PubChem Substance ID:
MDL number:
assay
97%
form
solid
mp
128-131 °C
functional group
hydroxyl, imine
SMILES string
CC(C)(C)c1cc(\C=N\[C@@H]2[C@H](O)Cc3ccccc23)c(O)c(c1)C(C)(C)C
InChI
1S/C24H31NO2/c1-23(2,3)17-11-16(22(27)19(13-17)24(4,5)6)14-25-21-18-10-8-7-9-15(18)12-20(21)26/h7-11,13-14,20-21,26-27H,12H2,1-6H3/b25-14+/t20-,21+/m1/s1
InChI key
MMNHXVSQIRTBOZ-FOYRYCBESA-N
Application
(1S,2R)-1-[(3,5-Di-tert-butyl-2-hydroxybenzylidene)amino]-2-indanol can be used as a ligand to prepare Schiff-base chromium(III) complex, which is used as a catalyst in the synthesis of:
- Poly(cyclohexene carbonate) by coupling of CO2 and cyclohexene oxide.
- β-hydroxyenol ethers by asymmetric hetero-ene reaction between aryl aldehydes and 2-methoxypropene.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
COPOLYMERIZATION OF CO2 AND EPOXIDES CATALYZED BY A SCHIFF-BASE CHROMIUM(III) COMPLEX (2019)
Rebecca T Ruck et al.
Journal of the American Chemical Society, 124(12), 2882-2883 (2002-03-21)
Tridentate Schiff base chromium(III) complex 1 catalyzes the asymmetric hetero-ene reaction between aryl aldehydes and either 2-methoxypropene or 2-trimethylsilyloxypropene to provide a series of beta-hydroxyenol ether products in high yields and enantioselectivities. X-ray crystallographic analysis of a closely related chromium
Pellotier, B. et al.
Synlett, 1055-1055 (2002)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 644145-1G | 04061826698396 |