646636
(S)-(+)-COP-Cl 催化剂
登录查看公司和协议定价
选择尺寸
关于此项目
经验公式（希尔记法）:
C78H66Cl2Co2N2O2Pd2
化学文摘社编号:
分子量:
1464.98
MDL编号:
UNSPSC代码:
12352000
PubChem化学物质编号:
旋光性
[α]20/D +1201°, c = 0.1 in methylene chloride
mp
204-205 °C (lit.)
SMILES字符串
[Co].[Co].[Cl+]1[Pd-][Cl+][Pd-]1.CC(C)[C@@H]2COC(=N2)[C]3[CH][CH][CH][CH]3.CC(C)[C@@H]4COC(=N4)[C]5[CH][CH][CH][CH]5.c6ccc(cc6)[C]7[C]([C]([C]7c8ccccc8)c9ccccc9)c%10ccccc%10.c%11ccc(cc%11)[C]%12[C]([C]([C]%12c%13ccccc%13)c%14ccccc%14)c%15ccccc%15
InChI
1S/2C28H20.2C11H14NO.2Cl.2Co.2Pd/c2*1-5-13-21(14-6-1)25-26(22-15-7-2-8-16-22)28(24-19-11-4-12-20-24)27(25)23-17-9-3-10-18-23;2*1-8(2)10-7-13-11(12-10)9-5-3-4-6-9;;;;;;/h2*1-20H;2*3-6,8,10H,7H2,1-2H3;;;;;;/q;;;;2*+1;;;2*-1/t;;2*10-;;;;;;/m..00....../s1
InChI key
OSHCXJIQKOINDY-TWWPWAOZSA-N
应用
用于钯催化重排三氯乙酰亚胺烯丙酯生成高对映纯烯丙胺的配体。
Catalyst for:
- Enantioselective allylation of phenols with (E)-allylic alcohols to branched chiral allylic aryl ethers
- Asymmetric aza-Claisen rearrangement and ring-closing metathesis
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Carolyn E Anderson et al.
Journal of the American Chemical Society, 125(41), 12412-12413 (2003-10-09)
COP-Cl catalyzes the rearrangement of (E)-allylic trichloroacetimidates to provide transposed allylic trichloroacetamides of high enantiopurity, a transformation that underlies the first truly practical method for transforming prochiral allylic alcohols to enantioenriched allylic amines and congeners. The high functional group compatibility
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持