658308
吗啉代硼氢化锂 溶液
1 M in THF
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关于此项目
经验公式（希尔记法）:
C4H11BLiNO
化学文摘社编号:
分子量:
106.89
UNSPSC Code:
12352005
PubChem Substance ID:
MDL number:
InChI
1S/C4H11BNO.Li/c5-6-1-3-7-4-2-6;/h1-4H2,5H3;/q-1;+1
SMILES string
[Li+].C[B-](C)(C)N1CCOCC1
InChI key
FHKYRXRJDHFNMQ-UHFFFAOYSA-N
reaction suitability
reagent type: reductant
concentration
1 M in THF
refractive index
n20/D 1.489
density
0.877 g/mL at 25 °C
storage temp.
2-8°C
Application
在与卤代吡啶类化合物和伯烷基甲磺酸酯类化合物反应的情况下，LAB 可以转移胺部分。
能够还原各种官能团。
signalword
Danger
target_organs
Respiratory system
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
1.4 °F
flash_point_c
-17 °C
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 2
法规信息
新产品
此项目有
Shannon Thomas et al.
Organic letters, 5(21), 3867-3870 (2003-10-11)
[reaction: see text] Lithium aminoborohydride (LAB) reagents promote the amination of 2-fluoropyridine under mild reaction conditions, providing 2-(dialkylamino)pyridines in excellent yield and purity. Treatment of 2-fluoropyridine with 1.1 equiv of lithium aminoborohydride at room temperature affords complete conversion after 1
Fisher, G. B. et al
The Journal of Organic Chemistry, 59, 6378-6378 (1994)
Pasumansky, L. et al
Aldrichimica Acta, 38, 61-61 (2005)
S Thomas et al.
Organic letters, 3(24), 3915-3918 (2001-11-27)
Lithium aminoborohydride (LAB) reagents initiate the amination or reduction of alkyl methanesulfonate esters, as dictated by reaction conditions. Alkyl methanesulfonate esters treated with unhindered LABs provide tertiary amines in excellent yield. Reduction to the corresponding alkane is achieved using a
Saikia, P.P.
Synlett, 995-995 (2007)
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