662992
反式-1-庚烯-1-基硼酸频哪酯
97%
别名:
E-2-(1-Heptenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, 反-1-庚烯基硼酸频哪醇酯
方案
97%
折射率
n20/D 1.445
沸点
73-77 °C/0.4-0.5 mmHg
密度
0.875 g/mL at 25 °C
SMILES字符串
CCCCC\C=C\B1OC(C)(C)C(C)(C)O1
InChI
1S/C13H25BO2/c1-6-7-8-9-10-11-14-15-12(2,3)13(4,5)16-14/h10-11H,6-9H2,1-5H3/b11-10+
InChI key
XHEDFAYNMNXKGM-ZHACJKMWSA-N
应用
用于和烯烃类化合物进行钯催化交叉偶联反应的底物，生成取代 1,3-二烯类化合物。
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
222.8 °F - closed cup
闪点(°C)
106 °C - closed cup
个人防护装备
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
Kyung Soo Yoo et al.
Journal of the American Chemical Society, 128(50), 16384-16393 (2006-12-15)
We report herein the development of a general and mild protocol of oxygen-promoted Pd(II) catalysis resulting in the selective cross-couplings of alkenyl- and arylboron compounds with various olefins. Unlike most cross-coupling reactions, this new methodology works well even in the
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