664073
(S)-(+)-2,3,7,7a-四氢-7a-甲基-1H-茚-1,5(6H)-二酮
97%
别名:
(+)-5,6,7,8-四氢-8-甲基茚满-1,5-二酮, (+)-7,7a-二氢-7α,β-甲基-1,5(6H)-茚满二酮, (S)-(+)-Hajos-Parrish 二酮, (S)-Hajos 二酮, (S)-Hajos 酮, (S)-Hajos-Wiechert 酮
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About This Item
经验公式（希尔记法）:
C10H12O2
CAS Number:
分子量:
164.20
Beilstein:
1619112
MDL编号:
UNSPSC代码:
12352115
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
97%
表单
solid
mp
57-64 °C
官能团
ketone
SMILES字符串
C[C@]12CCC(=O)C=C1CCC2=O
InChI
1S/C10H12O2/c1-10-5-4-8(11)6-7(10)2-3-9(10)12/h6H,2-5H2,1H3/t10-/m0/s1
InChI key
FNYAZSZTENLTRT-JTQLQIEISA-N
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应用
(S)-(+)-Hajos-Parrish diketone can be used as a reactant in:
- The total synthesis of steroidal alkaloids cortistatins.
- The stereoselective preparation of hydroanthracenol and related polycyclic compounds via Ti(Oi-Pr)4-promoted photoenolization Diels-Alder reaction.
- The synthesis of γ,γ-disubstituted allyldiboron compounds by reacting with allylic 1,1-diboronate reagents via Cu-catalyzed borylation and 1,2-addition reaction.
警示用语：
Danger
危险分类
Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
靶器官
Respiratory system
储存分类代码
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
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