664073
(S)-(+)-2,3,7,7a-四氢-7a-甲基-1H-茚-1,5(6H)-二酮
97%
别名:
(+)-5,6,7,8-四氢-8-甲基茚满-1,5-二酮, (+)-7,7a-二氢-7α,β-甲基-1,5(6H)-茚满二酮, (S)-(+)-Hajos-Parrish 二酮, (S)-Hajos 二酮, (S)-Hajos 酮, (S)-Hajos-Wiechert 酮
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关于此项目
经验公式（希尔记法）:
C10H12O2
化学文摘社编号:
分子量:
164.20
UNSPSC Code:
12352115
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1619112
Assay:
97%
Form:
solid
InChI
1S/C10H12O2/c1-10-5-4-8(11)6-7(10)2-3-9(10)12/h6H,2-5H2,1H3/t10-/m0/s1
SMILES string
C[C@]12CCC(=O)C=C1CCC2=O
InChI key
FNYAZSZTENLTRT-JTQLQIEISA-N
assay
97%
form
solid
mp
57-64 °C
functional group
ketone
Quality Level
Application
(S)-(+)-Hajos-Parrish diketone can be used as a reactant in:
- The total synthesis of steroidal alkaloids cortistatins.
- The stereoselective preparation of hydroanthracenol and related polycyclic compounds via Ti(Oi-Pr)4-promoted photoenolization Diels-Alder reaction.
- The synthesis of γ,γ-disubstituted allyldiboron compounds by reacting with allylic 1,1-diboronate reagents via Cu-catalyzed borylation and 1,2-addition reaction.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
target_organs
Respiratory system
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
法规信息
新产品
此项目有
Cu-Catalyzed Diastereo-and Enantioselective Reactions of γ, γ-Disubstituted Allyldiboron Compounds with Ketones
Zanghi JM and Meek SJ
Angewandte Chemie (International ed. in English), 8(1), 1-10 (2020)
Construction of key building blocks towards the synthesis of cortistatins
Indu S, et al.
Organic & Biomolecular Chemistry, 18(13), 2432-2446 (2020)
Singlet oxygen-mediated selective C--H bond hydroperoxidation of ethereal hydrocarbons
Sagadevan A, et al.
Nature Communications, 8(1), 1-8 (2017)
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