668923
二-μ-氯双[5-氯-2-[(4-氯苯基)(羟基亚氨基-κN)甲基]苯基-κC]钯二聚物
97%
别名:
Nájera 催化剂 I, 二-氯双[5-氯-2-[(4-氯苯基)(羟基亚氨基)甲基]苯基-C]二钯
选择尺寸
关于此项目
SMILES string
O\N=C(/c1ccc(Cl)cc1)c2ccc(Cl)cc2[Pd]Cl.O\N=C(/c3ccc(Cl)cc3)c4ccc(Cl)cc4[Pd]Cl
InChI
1S/2C13H8Cl2NO.2ClH.2Pd/c2*14-11-5-1-9(2-6-11)13(16-17)10-3-7-12(15)8-4-10;;;;/h2*1-3,5-8,17H;2*1H;;/q;;;;2*+1/p-2/b2*16-13+;;;;
InChI key
GIMFEGPTUHULMU-VAABLSLRSA-L
assay
97%
form
solid
reaction suitability
core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
Application
- Suzuki coupling
- Suzuki-Miyaura coupling
- Najera palladacycle-catalyzed intermolecular Heck reaction of Morita-Baylis-Hillman adducts
- Hiyama cross-coupling
- Palladium-catalyzed acylation of terminal alkynes with acid chlorides
- Copper and amine free Sonogashira coupling reaction
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
商品
Palladacyclic catalysts by Bedford's group facilitate coupling reactions with low catalyst loadings and challenging aryl chlorides.
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