668923
二-μ-氯双[5-氯-2-[(4-氯苯基)(羟基亚氨基-κN)甲基]苯基-κC]钯二聚物
97%
别名:
Nájera 催化剂 I, 二-氯双[5-氯-2-[(4-氯苯基)(羟基亚氨基)甲基]苯基-C]二钯
方案
97%
表单
solid
反应适用性
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
SMILES字符串
O\N=C(/c1ccc(Cl)cc1)c2ccc(Cl)cc2[Pd]Cl.O\N=C(/c3ccc(Cl)cc3)c4ccc(Cl)cc4[Pd]Cl
InChI
1S/2C13H8Cl2NO.2ClH.2Pd/c2*14-11-5-1-9(2-6-11)13(16-17)10-3-7-12(15)8-4-10;;;;/h2*1-3,5-8,17H;2*1H;;/q;;;;2*+1/p-2/b2*16-13+;;;;
InChI key
GIMFEGPTUHULMU-VAABLSLRSA-L
应用
- Suzuki coupling
- Suzuki-Miyaura coupling
- Najera palladacycle-catalyzed intermolecular Heck reaction of Morita-Baylis-Hillman adducts
- Hiyama cross-coupling
- Palladium-catalyzed acylation of terminal alkynes with acid chlorides
- Copper and amine free Sonogashira coupling reaction
警示用语：
Warning
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
商品
Palladacyclic catalysts by Bedford's group facilitate coupling reactions with low catalyst loadings and challenging aryl chlorides.
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