方案
97%
表单
solid
mp
133 °C (dec.)
官能团
amine
phenyl
储存温度
2-8°C
SMILES字符串
[Cl-].C[NH2+]OC(=O)c1ccccc1
InChI
1S/C8H9NO2.ClH/c1-9-11-8(10)7-5-3-2-4-6-7;/h2-6,9H,1H3;1H
InChI key
FTCDQNQIGUCFSA-UHFFFAOYSA-N
应用
用于醛和酮的 α-酰氧基化的试剂。对空气和湿度不敏感。
Benzoylation Reagents Simple Tools for a-Oxygenation of Aldehydes and Ketones
Reactant for preparation of:
Reactant for preparation of:
- NHC-catalyzed redox esterification and cycloaddition reactions
- Pd/pyrrolidine-catalyzed Tsuji-Trost cyclization of aldehydes
- α-acyloxy ketones via oxyacylation reaction
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
新产品
Cory S Beshara et al.
Organic letters, 7(25), 5729-5732 (2005-12-03)
[chemical reaction: see text]. A simple, one-pot method for the alpha-acyloxylation of carbonyl compounds that proceeds at room temperature in the presence of both moisture and air has been developed. Treatment of a variety of aldehydes and both cyclic and
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