669393
N-甲基-O-苯基羟胺盐酸盐
97%
别名:
N-羟基甲基氨基苯甲酸酯盐酸盐
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关于此项目
线性分子式:
(C6H5)CO2(NHCH3) HCl
化学文摘社编号:
分子量:
187.62
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22
Assay:
97%
Form:
solid
SMILES string
[Cl-].C[NH2+]OC(=O)c1ccccc1
InChI
1S/C8H9NO2.ClH/c1-9-11-8(10)7-5-3-2-4-6-7;/h2-6,9H,1H3;1H
InChI key
FTCDQNQIGUCFSA-UHFFFAOYSA-N
assay
97%
form
solid
mp
133 °C (dec.)
functional group
amine, phenyl
storage temp.
2-8°C
Application
用于醛和酮的 α-酰氧基化的试剂。对空气和湿度不敏感。
Benzoylation Reagents Simple Tools for a-Oxygenation of Aldehydes and Ketones
Reactant for preparation of:
Reactant for preparation of:
- NHC-catalyzed redox esterification and cycloaddition reactions
- Pd/pyrrolidine-catalyzed Tsuji-Trost cyclization of aldehydes
- α-acyloxy ketones via oxyacylation reaction
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
新产品
此项目有
Cory S Beshara et al.
Organic letters, 7(25), 5729-5732 (2005-12-03)
[chemical reaction: see text]. A simple, one-pot method for the alpha-acyloxylation of carbonyl compounds that proceeds at room temperature in the presence of both moisture and air has been developed. Treatment of a variety of aldehydes and both cyclic and
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