方案
95%
表单
liquid
旋光性
[α]20/D +98±5°, c = 0.7 in chloroform
反应适用性
reaction type: click chemistry
折射率
n20/D 1.5205
官能团
ether
phenyl
SMILES字符串
CO[C@]1(C)C[C@]2(C)C=C(Cc3ccccc3)[C@H]1C=C2CC(C)C
InChI
1S/C22H30O/c1-16(2)11-19-13-20-18(12-17-9-7-6-8-10-17)14-21(19,3)15-22(20,4)23-5/h6-10,13-14,16,20H,11-12,15H2,1-5H3/t20-,21+,22-/m1/s1
InChI key
ACWLDJOHMGJACE-BHIFYINESA-N
应用
(1R, 4R, 8R) Carreira DOLEFIN Ligand is a chiral diene ligand that can be used in:
- The asymmetric Rh-catalyzed arylation of alkenylheterocycles by conjugate additions with various aryl boronic acids.[1]
- The enantioselective synthesis of 3,3-diarylpropanals by conjugate addition of aromatic boronic acids to cinnamaldehyde derivatives in the presence of a rhodium catalyst.[2]
- The asymmetric synthesis of pyrrolizidinones by rhodium-catalyzed 1,4-addition of aryl boronic acids to pyrrolidine acceptor.[3]
包装
Bottomless glass bottle. Contents are inside inserted fused cone.
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves
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