669857
(R)-S-甲基-S-苯基-N-{2-[(2,4,6-三异丙基苯基)甲基氨基]苯基}砜亚胺
≥97.0% (HPLC)
别名:
(R)-N-[2-(2,4,6-三异丙基苄基氨基)-苯基]-S-甲基-S-苯基砜亚胺
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关于此项目
经验公式（希尔记法）:
C29H38N2OS
化学文摘社编号:
分子量:
462.69
UNSPSC Code:
12352005
PubChem Substance ID:
MDL number:
InChI
1S/C29H38N2OS/c1-20(2)23-17-25(21(3)4)27(26(18-23)22(5)6)19-30-28-15-11-12-16-29(28)31-33(7,32)24-13-9-8-10-14-24/h8-18,20-22,30H,19H2,1-7H3/t33-/m1/s1
SMILES string
CC(C)c1cc(C(C)C)c(CNc2ccccc2N=[S@](C)(=O)c3ccccc3)c(c1)C(C)C
InChI key
RWBXYWODTYKLEN-MGBGTMOVSA-N
assay
≥97.0% (HPLC)
optical purity
enantiomeric ratio: ≥99:1
mp
124-127 °C
Application
铜的配体，用于不对称羟醛反应。
Packaging
Bottomless glass bottle. Contents are inside inserted fused cone.
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Martin Langner et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 11(21), 6254-6265 (2005-08-03)
The development of C1-symmetric aminosulfoximines, their highly modular synthesis, and their application in enantioselective copper-catalyzed Mukaiyama-type aldol reactions between pyruvates and enolsilanes is described. In this context, the influence of the ligand architecture as well as the optimization of the
Pauline Rémy et al.
Organic letters, 8(6), 1209-1211 (2006-03-10)
[reaction: see text] gamma,delta-Unsaturated alpha-hydroxy diesters with quaternary centers have been obtained with up to 99% ee in high yields using catalysts prepared from copper(II) triflate and C(1)-symmetric aminosulfoximines.
C(1)-symmetric sulfoximines as ligands in copper-catalyzed asymmetric Mukaiyama-type aldol reactions.
Martin Langner et al.
Angewandte Chemie (International ed. in English), 43(44), 5984-5987 (2004-11-18)
Okamura, H.; Bolm, C.
Chemistry Letters (Jpn), 33, 482-482 (2004)
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