669857
(R)-S-甲基-S-苯基-N-{2-[(2,4,6-三异丙基苯基)甲基氨基]苯基}砜亚胺
≥97.0% (HPLC)
别名:
(R)-N-[2-(2,4,6-三异丙基苄基氨基)-苯基]-S-甲基-S-苯基砜亚胺
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选择尺寸
关于此项目
经验公式（希尔记法）:
C29H38N2OS
化学文摘社编号:
分子量:
462.69
UNSPSC Code:
12352005
PubChem Substance ID:
MDL number:
InChI
1S/C29H38N2OS/c1-20(2)23-17-25(21(3)4)27(26(18-23)22(5)6)19-30-28-15-11-12-16-29(28)31-33(7,32)24-13-9-8-10-14-24/h8-18,20-22,30H,19H2,1-7H3/t33-/m1/s1
SMILES string
CC(C)c1cc(C(C)C)c(CNc2ccccc2N=[S@](C)(=O)c3ccccc3)c(c1)C(C)C
InChI key
RWBXYWODTYKLEN-MGBGTMOVSA-N
assay
≥97.0% (HPLC)
optical purity
enantiomeric ratio: ≥99:1
mp
124-127 °C
Application
铜的配体，用于不对称羟醛反应。
Packaging
Bottomless glass bottle. Contents are inside inserted fused cone.
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Pauline Rémy et al.
Organic letters, 8(6), 1209-1211 (2006-03-10)
[reaction: see text] gamma,delta-Unsaturated alpha-hydroxy diesters with quaternary centers have been obtained with up to 99% ee in high yields using catalysts prepared from copper(II) triflate and C(1)-symmetric aminosulfoximines.
Martin Langner et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 11(21), 6254-6265 (2005-08-03)
The development of C1-symmetric aminosulfoximines, their highly modular synthesis, and their application in enantioselective copper-catalyzed Mukaiyama-type aldol reactions between pyruvates and enolsilanes is described. In this context, the influence of the ligand architecture as well as the optimization of the
C(1)-symmetric sulfoximines as ligands in copper-catalyzed asymmetric Mukaiyama-type aldol reactions.
Martin Langner et al.
Angewandte Chemie (International ed. in English), 43(44), 5984-5987 (2004-11-18)
Okamura, H.; Bolm, C.
Chemistry Letters (Jpn), 33, 482-482 (2004)
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