669873
(Λ,R)-BINPHAT
≥95.0% (31P-NMR)
别名:
[四丁铵][(Λ,R)-(1,1′-联萘-2,2′二醇酸根)(双(四氯-1,2-苯二醇酸根)磷酸盐(V))]
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选择尺寸
关于此项目
经验公式（希尔记法）:
C32H12Cl8O6P · C16H36N
分子量:
1049.50
UNSPSC Code:
12352000
PubChem Substance ID:
MDL number:
InChI
1S/C32H12Cl8O6P.C16H36N/c33-21-22(34)26(38)30-29(25(21)37)43-47(44-30,45-31-27(39)23(35)24(36)28(40)32(31)46-47)41-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)42-47;1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4/h1-12H;5-16H2,1-4H3/q-1;+1
SMILES string
CCCC[N+](CCCC)(CCCC)CCCC.Clc1c(Cl)c(Cl)c2O[P-]34(Oc5ccc6ccccc6c5-c7c(O3)ccc8ccccc78)(Oc2c1Cl)Oc9c(Cl)c(Cl)c(Cl)c(Cl)c9O4
InChI key
YJHXQLMGOKCETI-UHFFFAOYSA-N
assay
≥95.0% (31P-NMR)
impurities
≤5.0% Δ-TRISPHAT tetrabutylammonium salt
storage temp.
2-8°C
Application
Chiral anion mediated asymmetric chemistry
Packaging
Bottomless glass bottle. Contents are inside inserted fused cone.
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Jérôme Lacour et al.
Chemical Society reviews, 32(6), 373-382 (2003-12-16)
Chemical reactions and processes often involve cationic prostereogenic or racemic reagents, intermediates or products. To afford instead non-racemic or enantiopure compounds, an asymmetric ion pairing of the cations with chiral anionic counterions can be considered. This review presents recent examples
Jerome Lacour et al.
Organic & biomolecular chemistry, 3(1), 15-19 (2004-12-17)
Chemical reactions and processes often involve chiral, yet racemic, cationic reagents, intermediates or products. To afford instead non racemic or enantiopure compounds, an asymmetric ion pairing of the cations with enantiopure anions can be considered--the counter ions behaving as asymmetric
Chiral ion mediated asym. chemistry
Lacour, J.
Chimia, 56, 672-675 (2002)
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