669873
(Λ,R)-BINPHAT
≥95.0% (31P-NMR)
别名:
[四丁铵][(Λ,R)-(1,1′-联萘-2,2′二醇酸根)(双(四氯-1,2-苯二醇酸根)磷酸盐(V))]
方案
≥95.0% (31P-NMR)
杂质
≤5.0% Δ-TRISPHAT tetrabutylammonium salt
储存温度
2-8°C
SMILES字符串
CCCC[N+](CCCC)(CCCC)CCCC.Clc1c(Cl)c(Cl)c2O[P-]34(Oc5ccc6ccccc6c5-c7c(O3)ccc8ccccc78)(Oc2c1Cl)Oc9c(Cl)c(Cl)c(Cl)c(Cl)c9O4
InChI
1S/C32H12Cl8O6P.C16H36N/c33-21-22(34)26(38)30-29(25(21)37)43-47(44-30,45-31-27(39)23(35)24(36)28(40)32(31)46-47)41-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)42-47;1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4/h1-12H;5-16H2,1-4H3/q-1;+1
InChI key
YJHXQLMGOKCETI-UHFFFAOYSA-N
应用
Chiral anion mediated asymmetric chemistry
包装
Bottomless glass bottle. Contents are inside inserted fused cone.
储存分类代码
13 - Non Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Jérôme Lacour et al.
Chemical Society reviews, 32(6), 373-382 (2003-12-16)
Chemical reactions and processes often involve cationic prostereogenic or racemic reagents, intermediates or products. To afford instead non-racemic or enantiopure compounds, an asymmetric ion pairing of the cations with chiral anionic counterions can be considered. This review presents recent examples
Jerome Lacour et al.
Organic & biomolecular chemistry, 3(1), 15-19 (2004-12-17)
Chemical reactions and processes often involve chiral, yet racemic, cationic reagents, intermediates or products. To afford instead non racemic or enantiopure compounds, an asymmetric ion pairing of the cations with enantiopure anions can be considered--the counter ions behaving as asymmetric
Chiral ion mediated asym. chemistry
Lacour, J.
Chimia, 56, 672-675 (2002)
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