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关于此项目
经验公式(希尔记法):
C22H24NP
化学文摘社编号:
分子量:
333.41
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
InChI
1S/C22H24NP/c1-4-22(2,3)20-16-11-17-21(23-20)24(18-12-7-5-8-13-18)19-14-9-6-10-15-19/h5-17H,4H2,1-3H3
SMILES string
CCC(C)(C)c1cccc(n1)P(c2ccccc2)c3ccccc3
InChI key
ZEQMNGUCEYRQRF-UHFFFAOYSA-N
assay
≥98.0% (HPLC)
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
mp
78-82 °C
functional group
phosphine
storage temp.
2-8°C
Application
用于催化:
- 寡聚1,4-二醇的区域选择性合成
- 反马氏水和反应
hcodes
Hazard Classifications
Aquatic Chronic 4
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Aurélie Labonne et al.
Organic letters, 8(25), 5853-5856 (2006-12-01)
The anti-Markovnikov hydration of terminal alkynes to give aldehydes is catalyzed by complexes derived in situ from air-stable [CpRu(eta6-naphthalene)]PF6 (C) and 6-aryl-2-diphenylphosphinopyridines (L). Ligands L are readily available from a modular synthesis. Increasing the size of the ligand C-6 aryl
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