673366
2,2′-[(1S,2S)-1,2-环己二基双[(E)-(次氮基次甲基)]]双[4-(叔丁基)-6-(4-哌啶基甲基)苯酚]
97%
别名:
N,N′-双[(E)-5-(叔丁基)-2-羟基-3-4-哌啶基甲基)亚苄基]-[(1S,2S)-1,2-环己二胺]
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关于此项目
经验公式（希尔记法）:
C40H60N4O2
化学文摘社编号:
分子量:
628.93
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
方案
97%
表单
solid
mp
72-81 °C
官能团
imine
SMILES字符串
CC(C)(C)c1cc(CN2CCCCC2)c(O)c(\C=N\[C@H]3CCCC[C@@H]3\N=C\c4cc(cc(CN5CCCCC5)c4O)C(C)(C)C)c1
InChI
1S/C40H60N4O2/c1-39(2,3)33-21-29(37(45)31(23-33)27-43-17-11-7-12-18-43)25-41-35-15-9-10-16-36(35)42-26-30-22-34(40(4,5)6)24-32(38(30)46)28-44-19-13-8-14-20-44/h21-26,35-36,45-46H,7-20,27-28H2,1-6H3/b41-25+,42-26+/t35-,36-/m0/s1
InChI key
QWZFCHMBYWXSLV-HKPCBFNZSA-N
应用
2,2′-[(1S,2S)-1,2-Cyclohexanediylbis[(E)-(nitrilomethylidyne)]]bis[4-(tert-butyl)-6-(1-piperidinylmethyl)phenol] can be used:
- In the synthesis of chiral Ru(II) salen complexes, which are employed in the binding studies with calf thymus DNA.
- To prepare its titanium metal complexes, which are used as catalysts in the addition of organozinc compounds to α-aldiminoesters and α-ketoesters.
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
The first catalytic asymmetric addition of dialkylzincs to α-ketoesters
DiMauro EF and Kozlowski MC
Organic Letters, 4(22), 3781-3784 (2002)
Synthesis, characterization, DNA binding and cleavage studies of chiral Ru (II) salen complexes
Noor-ul HK, et al.
Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy, 74(1), 113-119 (2009)
Catalytic asymmetric addition of dialkylzinc reagents to α-aldiminoesters
Basra S, et al.
Organic Letters, 8(13), 2659-2662 (2006)
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