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Merck
CN

675679

1-甲基-2-(三丁基锡基)吡咯

95%

别名:

(1-甲基吡咯-2-基)三丁基锡, 2-(三丁基锡基)-1-甲基吡咯, N-甲基-2-(三丁基锡基)吡咯

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关于此项目

线性分子式:
[H3C(C4H3N)]Sn[(CH2)3CH3]3
化学文摘社编号:
分子量:
370.16
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
Assay:
95%
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InChI

1S/C5H6N.3C4H9.Sn/c1-6-4-2-3-5-6;3*1-3-4-2;/h2-4H,1H3;3*1,3-4H2,2H3;

SMILES string

CCCC[Sn](CCCC)(CCCC)c1cccn1C

InChI key

DINAKCGOEKXDTP-UHFFFAOYSA-N

assay

95%

refractive index

n20/D 1.5107

density

1.1223 g/mL at 25 °C

storage temp.

−20°C

Application

1-Methyl-2-(tributylstannyl)pyrrole can be used as a reactant to prepare:
  • Bithienylpyrrole derivatives through a Stille coupling reaction with bithienyl bromides in the presence of Pd catalyst.
  • Di(bisthienyl)-o-carborane (DBTC) by reacting with 5,5′-dibromo-o-carboranyl-bisthiophenes using Pd catalyst. DBTC is electropolymerized to produce conducting polymers.
  • Poly(Py-BTz-Py) (2-butyl-4,7-bis(1-methyl-1H-pyrrol-2-yl)-2H-benzo[d][1,2,3]triazole) via Stille coupling reaction. Poly(Py-BTz-Py) can be used as an organic photocatalyst for the formation C-C bond under visible light irradiation.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 1

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

208.9 °F - closed cup

flash_point_c

98.3 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Synthesis and electropolymerization of a series of 2, 2?-(ortho-carboranyl) bisthiophenes
Zhao N, et al.
Journal of Organometallic Chemistry, 828(15), 157- 165 (2017)
Molecular Design of Donor-Acceptor-Type Organic Photocatalysts for Metal-free Aromatic C- C Bond Formations under Visible Light
Wang L, et al.
advanced synthesis and catalysis, 360(22), 4312- 4318 (2018)
Molecular Design of Donor-Acceptor-Type Organic Photocatalysts for Metal-free Aromatic C- C Bond Formations under Visible Light
Wang L, et al.
Advanced Synthesis & Catalysis, 360(22), 4312- 4318 (2018)
Synthesis of π-conjugated systems bearing thiophene and pyrrole heterocycles through palladium catalyzed cross-coupling reactions
Castro MCR and Raposo MMM
Tetrahedron, 72(15), 1881-1887 (2016)

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