方案
95%
表单
solid
反应适用性
reagent type: ligand
mp
122.2-131.9 °C
SMILES字符串
CC(C)(C)c1cc(\C=N\C(C(=O)O[K])(c2ccccc2)c3ccccc3)c(O)c(c1)C(C)(C)C
InChI
1S/C29H33NO3.K/c1-27(2,3)23-17-20(25(31)24(18-23)28(4,5)6)19-30-29(26(32)33,21-13-9-7-10-14-21)22-15-11-8-12-16-22;/h7-19,31H,1-6H3,(H,32,33);/q;+1/p-1/b30-19+;
InChI key
ZPKNCDGWTMRAKF-QUIZVCAPSA-M
应用
Hydroazidation Catalyst for Facile Preparation of Organoazides
SALDIPAC ligand used with Co(BF4)2 (cat. no. 399957) in a hydroazidation of unactivated olefins providing a simple synthesis of alkylazides. The azides, in turn, can be used in a copper-catalyzed cycloaddition with acetylenes providing 1,4-disubstitutedtriazoles.
SALDIPAC ligand used with Co(BF4)2 (cat. no. 399957) in a hydroazidation of unactivated olefins providing a simple synthesis of alkylazides. The azides, in turn, can be used in a copper-catalyzed cycloaddition with acetylenes providing 1,4-disubstitutedtriazoles.
储存分类代码
13 - Non Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
新产品
此项目有
Jérôme Waser et al.
Journal of the American Chemical Society, 127(23), 8294-8295 (2005-06-09)
Conversion of olefins to azides was achieved with high Markovnikov selectivity for a broad range of alkenes using 6 mol % Co(BF4).6H2O and ligand 1, with 3 equiv of TsN3 as nitrogen source and simple silanes (PhSiH3, TMDSO).
Synthesis, 3839-3839 (2007)
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