optical activity
[α]20/D −35 to ±5°, c = 1
concentration
1 M in dioxane
bp
100-102 °C
density
0.964 g/mL at 25 °C
SMILES string
C[C@H]1[C@@H](C[C@@H]2C[C@H]1C2(C)C)B(CC=C)[C@@H]3C[C@@H]4C[C@H]([C@H]3C)C4(C)C
InChI
1S/C23H39B/c1-8-9-24(20-12-16-10-18(14(20)2)22(16,4)5)21-13-17-11-19(15(21)3)23(17,6)7/h8,14-21H,1,9-13H2,2-7H3/t14-,15-,16+,17+,18-,19-,20-,21-/m1/s1
InChI key
ZIXZBDJFGUIKJS-RLEROFIGSA-N
General description
本品冷却储藏时可能会变浑浊，不影响使用
Application
方便、无盐且稳定的手性烯丙基硼烷溶液，用于醛的不对称烯丙基化反应，生成手性高烯丙醇。
signalword
Danger
hcodes
Hazard Classifications
Carc. 1B - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
53.6 °F - closed cup
flash_point_c
12 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Aldrichimica Acta, 35, 23-23 (2002)
Toward the total synthesis of spirastrellolide A. Part 1: Strategic considerations and preparation of the southern domain.
Alois Fürstner et al.
Angewandte Chemie (International ed. in English), 45(33), 5506-5510 (2006-07-11)