679879
S,S-二甲基 N-(2,2,2-三氯乙氧基磺酰基)甲酰亚胺连二硫酸酯
97%
别名:
[(2,2,2-三氯乙氧基)磺酰基)]-甲酰亚胺连二硫酸二甲酯
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关于此项目
经验公式（希尔记法）:
C5H8Cl3NO3S3
化学文摘社编号:
分子量:
332.68
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352101
MDL number:
InChI
1S/C5H8Cl3NO3S3/c1-13-4(14-2)9-15(10,11)12-3-5(6,7)8/h3H2,1-2H3
SMILES string
CS\C(SC)=N/S(=O)(=O)OCC(Cl)(Cl)Cl
InChI key
YLVMQHRVOAWREM-UHFFFAOYSA-N
assay
97%
mp
69-73 °C
storage temp.
2-8°C
Application
用于制备胍基化试剂的原料。
用于铑催化形成胍的试剂。
- Reactant for oxidative cyclization reactions
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
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Editorial 2006: exciting and challenging times for organic letters.
Amos B Smith
Organic letters, 8(1), 1-2 (2005-12-31)
Mihyong Kim et al.
Organic letters, 8(6), 1073-1076 (2006-03-10)
[reaction: see text] Oxidative C-H amination of N-trichloroethoxysulfonyl-protected ureas and guanidines is demonstrated to proceed in high yield for tertiary and benzylic-derived substrates. The success of these reactions is predicated on the choice of the electron-withdrawn 2,2,2-trichloroethoxysulfonyl (Tces) protecting group
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