680214
4-(2-氧代乙基)哌啶-1-羧酸叔丁酯
97%
别名:
4-(2-Oxoethyl)piperidine-1-carboxylic acid, tert-butyl ester
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关于此项目
经验公式（希尔记法）:
C12H21NO3
化学文摘社编号:
分子量:
227.30
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
InChI
1S/C12H21NO3/c1-12(2,3)16-11(15)13-7-4-10(5-8-13)6-9-14/h9-10H,4-8H2,1-3H3
SMILES string
[H]C(=O)CC1CCN(CC1)C(=O)OC(C)(C)C
InChI key
PSRHRFNKESVOEL-UHFFFAOYSA-N
assay
97%
form
solid
mp
38-42 °C
application(s)
peptide synthesis
functional group
aldehyde
Application
用于合成 (S)-奎宁环-2-羧酸的结构单元。用于不对称有机催化 α-乙烯化反应的底物。
Reactant for synthesis of:
Reactant for:
- Pim-1 inhibitors
- Selective GPR119 agonists for type II diabetes
Reactant for:
- α-arylation of aldehydes
- Enantioselective α-benzylation of aldehydes via photoredox organocatalysis
- Enantioselective α−triflouromethylation of aldehydes
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
>230.0 °F
flash_point_c
> 110 °C
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Tetrahedron Letters, 47, 2515-2515 (2006)
Enantioselective organo-SOMO catalysis: the alpha-vinylation of aldehydes.
Hahn Kim et al.
Journal of the American Chemical Society, 130(2), 398-399 (2007-12-22)
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