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681059

2-甲基-6-硝基苯甲酸酐

Name: 2-甲基-6-硝基苯甲酸酐
Brand: ALDRICH

97%

别名:

MNBA

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关于此项目

经验公式（希尔记法）:

C₁₆H₁₂N₂O₇

化学文摘社编号:

434935-69-0

分子量:

344.28

NACRES:

NA.22

PubChem Substance ID:

24885612

UNSPSC Code:

12352108

MDL number:

MFCD06797117

Assay:

97%

Form:

solid

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属性

Quality Level

200

assay

97%

form

solid

mp

173-177 °C

functional group

anhydride, ester, nitro

SMILES string

Cc1cccc(c1C(=O)OC(=O)c2c(C)cccc2[N+]([O-])=O)[N+]([O-])=O

InChI

1S/C16H12N2O7/c1-9-5-3-7-11(17(21)22)13(9)15(19)25-16(20)14-10(2)6-4-8-12(14)18(23)24/h3-8H,1-2H3

InChI key

YEKPNMQQSPHKBP-UHFFFAOYSA-N

说明

General description

2-甲基-6-硝基苯甲酸酐可用作酰胺、内酯、酯和肽合成中的偶联促进剂。

Application

2-甲基-6-硝基苯甲酸酐可用于：

作为多功能的内酯化试剂用于制备各种大环内酯天然产物和内酯。
作为反应促进剂采用相应的胺和羧酸合成羧酰胺衍生物。
GRP78 抑制剂 prunustatin A、抗真菌化合物 (3R,16E,20E,23R)-(−)-eushearilide 和防肥胖药四氢利泼斯汀的全合成。

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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The first total synthesis of (-) and (+)-2-hydroxy-24-oxooctacosanolide using an effective lactonization

Shiina I, et al.

Organic Letters, 8(21), 4955-4958 (2006)

4-(Dimethylamino)pyridine N-Oxide-Catalyzed Macrolactamization Using 2-Methyl-6-nitrobenzoic Anhydride in the Synthesis of the Depsipeptidic Analogue of FE399.

Takayuki Tonoi et al.

ACS omega, 6(5), 3571-3577 (2021-02-16)

A depsipeptidic analogue of FE399 was efficiently synthesized mainly through macrolactamization using 2-methyl-6-nitrobenzoic anhydride (MNBA), and a detailed investigation of the desired 16-membered macrolactam core of FE399 was performed. It was determined that the combination of MNBA and a catalytic

Sensitive and simultaneous quantitation of 6β-hydroxycortisol and cortisol in human plasma by LC-MS/MS coupled with stable isotope dilution method.

Ryohei Hirano et al.

Journal of mass spectrometry : JMS, 53(8), 665-674 (2018-05-17)

CYP3A phenotyping provides a means for personalized drug therapy. We focused our attention on the plasma 6β-hydroxycortisol (6β-OHF) to cortisol ratio as an index for CYP3A phenotyping. In the present study, we developed a sensitive and reliable method for the

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全球贸易项目编号

货号	GTIN
681059-10G	04061833549902
681059-1G	04061826733622