682675
2-异丁酰基环己酮
96%, liquid
别名:
2-(2-甲基-1-氧代丙烷)环己酮
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关于此项目
经验公式（希尔记法）:
C10H16O2
化学文摘社编号:
分子量:
168.23
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
2-异丁酰基环己酮, 96%
SMILES string
CC(C)C(=O)C1CCCCC1=O
InChI
1S/C10H16O2/c1-7(2)10(12)8-5-3-4-6-9(8)11/h7-8H,3-6H2,1-2H3
InChI key
PFOYYSGBGILOQZ-UHFFFAOYSA-N
assay
96%
form
liquid
reaction suitability
reagent type: ligand
refractive index
n20/D 1.5006
density
1.0076 g/mL at 25 °C
functional group
ketone
Quality Level
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
219.9 °F - closed cup
flash_point_c
104.4 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
An alternative to the classical α-arylation: the transfer of an intact 2-iodoaryl from ArI(O₂CCF₃)₂.
Zhiyu Jia et al.
Angewandte Chemie (International ed. in English), 53(42), 11298-11301 (2014-09-10)
The α-arylation of carbonyl compounds is generally accomplished under basic conditions, both under metal catalysis and via aryl transfer from the diaryl λ(3)-iodanes. Here, we describe an alternative metal-free α-arylation using ArI(O2CCF3)2 as the source of a 2-iodoaryl group. The
Yoshihide Usami et al.
Molecules (Basel, Switzerland), 25(20) (2020-10-16)
Alkylamino coupling reactions at the C4 positions of 4-halo-1H-1-tritylpyrazoles were investigated using palladium or copper catalysts. The Pd(dba)2 catalyzed C-N coupling reaction of aryl- or alkylamines, lacking a β-hydrogen atom, proceeded smoothly using tBuDavePhos as a ligand. As a substrate
商品
Buchwald phosphine ligands for C-C, C-N, and C-O bond formation.
Buchwald phosphine ligands for C-C, C-N, and C-O bond formation.
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