InChI
1S/6C13H19NO4.C8H16N2O.C2HF3O2/c6*1-5-17-12(15)10-7-11(13(16)18-6-2)9(4)14-8(10)3;1-8(2,3)7-9-5-6(11)10(7)4;3-2(4,5)1(6)7/h6*14H,5-7H2,1-4H3;7,9H,5H2,1-4H3;(H,6,7)/t;;;;;;7-;/m......0./s1
SMILES string
OC(=O)C(F)(F)F.CN1[C@H](NCC1=O)C(C)(C)C.CCOC(=O)C2=C(C)NC(C)=C(C2)C(=O)OCC.CCOC(=O)C3=C(C)NC(C)=C(C3)C(=O)OCC.CCOC(=O)C4=C(C)NC(C)=C(C4)C(=O)OCC.CCOC(=O)C5=C(C)NC(C)=C(C5)C(=O)OCC.CCOC(=O)C6=C(C)NC(C)=C(C6)C(=O)OCC.CCOC(=O)C7=C(C)NC(C)=C(C7)C(=O)OCC
InChI key
NWCRTIKSGFXFGW-KDCVMDMUSA-N
form
solid
Application
手性咪唑烷酮与 Hantzsch 乙酯的混合物；形式上将氢不对称转移到烯醛形成手性醛。
Legal Information
适用美国专利 6,369,243 和相关专利。仅供研究使用。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Stéphane G Ouellet et al.
Journal of the American Chemical Society, 127(1), 32-33 (2005-01-06)
The first enantioselective organocatalytic hydride reduction has been accomplished. The use of iminium catalysis has provided a new organocatalytic strategy for the enantioselective reduction of beta,beta-substituted alpha,beta-unsaturated aldehydes to generate beta-stereogenic aldehydes. The use of imidazolidinone 2 as the asymmetric
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