685615
溴三羰基（四氢呋喃）铼 (I) 二聚体
别名:
Dibromohexacarbonylbis(tetrahydrofuran)dirhenium
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关于此项目
线性分子式:
[ReBr(CO)3(C4H8O)]2
化学文摘社编号:
分子量:
844.49
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352300
MDL number:
InChI
1S/2C4H8O.6CO.2BrH.2Re/c2*1-2-4-5-3-1;6*1-2;;;;/h2*1-4H2;;;;;;;2*1H;;/q;;;;;;;;;;2*+1/p-2
SMILES string
Br[Re].Br[Re].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].C1CCOC1.C2CCOC2
InChI key
GARJHXMUDDMPBU-UHFFFAOYSA-L
form
powder
reaction suitability
core: rhenium, reagent type: catalyst
Application
用于将乙炔插入 1,3-二羰基以及合成异苯并呋喃的催化剂。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Yoichiro Kuninobu et al.
Journal of the American Chemical Society, 128(38), 12376-12377 (2006-09-21)
A rhenium complex, [ReBr(CO)3(thf)]2, catalyzed reactions of aromatic ketimines with aldehydes to give isobenzofuran derivatives in good to excellent yields. In contrast to ruthenium and rhodium catalysts, aldehydes, which are polar unsaturated molecules, inserted into the C-H bond after activation
Takai, K. et al.
Journal of the American Chemical Society, 128, 11369-11369 (2006)
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