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经验公式(希尔记法):
C20H25F6N2P
化学文摘社编号:
分子量:
438.39
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352101
MDL number:
InChI
1S/C20H25N2.F6P/c1-14(2)18-10-7-11-19(15(3)4)20(18)21-12-17-9-6-8-16(5)22(17)13-21;1-7(2,3,4,5)6/h6-15H,1-5H3;/q+1;-1
SMILES string
F[P-](F)(F)(F)(F)F.CC(C)c1cccc(C(C)C)c1-[n+]2cc3cccc(C)n3c2
InChI key
QMSMRHHBCWKWQO-UHFFFAOYSA-N
assay
95%
form
solid
reaction suitability
reagent type: catalyst
mp
246-256 °C
Application
稳定的 N-杂环卡宾前体。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Manuel Alcarazo et al.
Journal of the American Chemical Society, 127(10), 3290-3291 (2005-03-10)
The imidazo[1,5-a]pyridine skeleton provides a versatile platform for the generation of new types of stable N-heterocyclic carbenes. Rh(I) mono- (6) and biscarbenes (7) from imidazo[1,5-a]pyridin-3-ylidenes (ImPy) and derivatives such as 13 from a mesoionic carbene were synthesized and characterized.
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