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Merck
CN

689203

3,4-二羟基-3-环丁烯-1,2-二酮

Arxada quality, 98.50-101.00 % (w/w) (HPLC)

别名:

方形酸

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线性分子式:
(HO)2C4(=O)2
化学文摘社编号:
分子量:
114.06
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
220-761-4
Beilstein/REAXYS Number:
774275
MDL number:
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InChI

1S/C4H2O4/c5-1-2(6)4(8)3(1)7/h5-6H

InChI key

PWEBUXCTKOWPCW-UHFFFAOYSA-N

SMILES string

OC1=C(O)C(=O)C1=O

quality

Arxada quality

manufacturer/tradename

Arxada AG

concentration

98.50-101.00 % (w/w) (HPLC)

impurities

≤0.5 % (w/w) water (Karl Fischer)

mp

>300 °C (lit.)

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

374.0 °F

flash_point_c

190 °C

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

法规信息

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Elena Sanna et al.
Organic letters, 12(17), 3840-3843 (2010-08-10)
A minimalist squaramide-based chemodosimeter for Cu(2+) is described. Upon selective chelation to 2, Cu(2+) induces the formation of a highly colored zwitterionic radical, which is kinetically stable for hours. The presence of a radical is confirmed by EPR and ESI-MS.
Carsten Dingels et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(52), 16828-16835 (2012-11-09)
The covalent attachment of poly(ethylene glycol) (PEG) to therapeutically active proteins (PEGylation) has become an important method to deal with the pharmacological difficulties of these polypeptides, such as short body-residence times and immunogenicity. However, the derivatives of PEG used for
Dawei Cui et al.
Chemical communications (Cambridge, England), 47(4), 1348-1350 (2010-11-18)
We report a class of water-soluble and -stable cyclic amino squarates that ligate with cysteine or lysine residues without side-products in an entirely aqueous environment. The ligations include addition-elimination reactions that are promoted by water in a way similar to
Vijayakumar Ramalingam et al.
Organic letters, 10(15), 3315-3318 (2008-07-02)
Environment-sensitive binding of anions to synthetic receptors is important for the functional mimicry of ion channels. We describe new squaramide-based chloride ion receptors whose anion binding cavity can be opened and closed by using carbonyl groups as valves. In nonpolar
Jørn E Tungen et al.
Organic letters, 14(23), 5884-5887 (2012-11-15)
Asymmetric iodolactonization of γ- and δ-unsaturated carboxylic acids has been explored in the presence of six different chiral organocatalysts 5-8. The catalyst 6b was found to facilitate the cyclization of 5-arylhex-5-enoic acids 1 to the corresponding iodolactones 2 with up

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