691321
2-溴丙烯醛
95%
别名:
2-Bromo-acrylaldehyde, 2-Bromopropenal
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关于此项目
经验公式（希尔记法）:
C3H3BrO
化学文摘社编号:
分子量:
134.96
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1698247
InChI
1S/C3H3BrO/c1-3(4)2-5/h2H,1H2
SMILES string
BrC(=C)C=O
InChI key
MDSPECLCFVWIGQ-UHFFFAOYSA-N
assay
94.0-106.0% (AT), 95%
contains
~0.2% hydroquinone as stabilizer
storage temp.
−20°C
Packaging
Bottomless glass bottle. Contents are inside inserted fused cone.
signalword
Danger
Hazard Classifications
Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Aquatic Acute 1 - Eye Dam. 1 - Skin Corr. 1B
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
207.0 °F
flash_point_c
97.2 °C
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
G J van Beerendonk et al.
Mutagenesis, 7(1), 19-24 (1992-01-01)
DNA-adduct formation by the mutagen 2-bromoacrolein (2BA) with DNA was studied. [3-3H]2BA was reacted with single-stranded (ss) DNA or double-stranded (ds) DNA and subsequently incubated with methoxylamine to convert an unstable 2BA:thymidine adduct (Meerman et al., Cancer Res., 49, 6174-6179
P G Pearson et al.
Toxicology and applied pharmacology, 118(2), 186-195 (1993-02-01)
Analogs of tris(2,3-dibromopropyl)phosphate (Tris-BP) either labeled at specific positions with carbon-14, phosphorus-32, or oxygen-18 or dual-labeled with both deuterium and tritium were used as metabolic probes to study the chemical and metabolic events in the bioactivation of Tris-BP to chemically
G J van Beerendonk et al.
Cancer research, 54(3), 679-684 (1994-02-01)
Calf thymus single-stranded DNA was modified with 2-bromoacrolein (2BA), a genotoxic metabolite of tris(2,3-dibromopropyl)phosphate. This DNA was used as a template for in vitro DNA replication by T7-polymerase and Klenow fragment of Escherichia coli DNA polymerase I. Increasing levels of
A Chenna et al.
Carcinogenesis, 13(12), 2361-2365 (1992-12-01)
Thymidine was permitted to react with the known mutagens acrolein and 2-bromoacrolein under physiological conditions. The products of these reactions were separated by HPLC and characterized by UV, FAB/MS, electrospray MS, 1H NMR and chemical transformation. The reaction with acrolein
G J van Beerendonk et al.
Mutation research, 415(3), 201-211 (1998-08-26)
The flame retardant tris(2,3-dibromopropyl)phosphate (Tris-BP) and its metabolite 2-bromoacrolein (2BA) are very potent bacterial mutagens in Salmonella typhimurium (S. typhimurium) TA 100. In this study, we showed that 2BA and Tris-BP are also mutagenic in S. typhimurium TA 104, which
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