697761
(R,R)-DIPAMP
95%
别名:
(R,R)-1,2-乙烷二基双[(2-甲氧基苯基)苯基膦], (R,R)-1,2-双[(2-甲氧基苯基)(苯基膦基)]乙烷, (R,R)-乙烯二[(2-甲氧基苯基)苯基膦], [(1R,2R)-(-)-双[(2-甲氧基苯基)苯基膦]乙烷]
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关于此项目
线性分子式:
[CH3OC6H4P(C6H5)CH2-]2
化学文摘社编号:
分子量:
458.47
MDL编号:
UNSPSC代码:
12352112
PubChem化学物质编号:
NACRES:
NA.22
方案
95%
表单
solid
旋光性
[α]22/D −81°, c = 1 in chloroform
mp
102-106 °C (lit.)
官能团
phosphine
SMILES字符串
COc1ccccc1P(CCP(c2ccccc2)c3ccccc3OC)c4ccccc4
InChI
1S/C28H28O2P2/c1-29-25-17-9-11-19-27(25)31(23-13-5-3-6-14-23)21-22-32(24-15-7-4-8-16-24)28-20-12-10-18-26(28)30-2/h3-20H,21-22H2,1-2H3/t31-,32-/m1/s1
InChI key
QKZWXPLBVCKXNQ-ROJLCIKYSA-N
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应用
(R, R)-DIPAMP can be used:
- As a catalyst in the enantioselective [3+2] cycloaddition of γ-substituted allenoates with β-perfluoroalkyl enones and 3-butynoates with electron-deficient olefins to yield substituted cyclopentenes.
- To prepare its rhodium metal complexes, which are used as catalysts in asymmetric hydrogenation reactions.
警示用语：
Warning
危险分类
Aquatic Chronic 4 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Phosphine-catalyzed enantioselective [3+2] cycloadditions of γ-substituted allenoates with β-perfluoroalkyl enones
Zhou W, et al.
Chemical Science, 8(6), 4660-4665 (2017)
Effect of gas-liquid mass transfer on enantioselectivity in asymmetric hydrogenations
Pestre N, et al.
J. Mol. Catal. A: Chem., 252(1-2), 85-89 (2006)
Development of an Asymmetric Hydrogenation Route to (S)-N-Boc-2, 6-Dimethyltyrosine
Praquin C, et al.
Organic Process Research & Development, 15(5), 1124-1129 (2011)
Highly enantio-, regio-and diastereo-selective one-pot [2+ 3]-cycloaddition reaction via isomerization of 3-butynoates to allenoates
Sampath M and Loh T
Chemical Science, 1(6), 739-742 (2010)
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