699292
反式-2-苯基乙烯基硼酸甲基亚氨基二乙酸酯
95%
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关于此项目
经验公式（希尔记法）:
C13H14BNO4
化学文摘社编号:
分子量:
259.07
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22
方案
95%
表单
powder
mp
185-195 °C
SMILES字符串
CN1CC(=O)OB(OC(=O)C1)\C=C\c2ccccc2
InChI
1S/C13H14BNO4/c1-15-9-12(16)18-14(19-13(17)10-15)8-7-11-5-3-2-4-6-11/h2-8H,9-10H2,1H3/b8-7+
InChI key
OFLDLTAQNBBGGU-BQYQJAHWSA-N
应用
trans-2-Phenylvinylboronic acid MIDA ester is a stable boronic acid surrogate, which can be used as a reactant in Suzuki-Miyaura cross-coupling reactions . It is also used as a precursor to prepare α-borylated phenyl ketone via the Wacker-type oxidation method.
储存分类代码
13 - Non Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
Synthesis of ?-borylated ketones by regioselective wacker oxidation of alkenylboronates
Corless VB, et al.
Organic Letters, 20(17), 5300-5303 (2018)
Nicholas A Isley et al.
Journal of the American Chemical Society, 135(47), 17707-17710 (2013-11-15)
New technology has been developed that enables Suzuki-Miyaura couplings involving widely utilized MIDA boronates to be run in water as the only medium, mainly at room temperature. The protocol is such that no organic solvent is involved at any stage;
Panchanan Maiti et al.
International journal of molecular sciences, 21(18) (2020-09-17)
Alzheimer's disease (AD) is characterized by amyloid (Aβ) aggregation, hyperphosphorylated tau, neuroinflammation, and severe memory deficits. Reports that certain boronic compounds can reduce amyloid accumulation and neuroinflammation prompted us to compare trans-2-phenyl-vinyl-boronic-acid-MIDA-ester (TPVA) and trans-beta-styryl-boronic-acid (TBSA) as treatments of deficits
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