方案
97%
表单
powder
反应适用性
reaction type: click chemistry
reagent type: catalyst
mp
168-170 °C
储存温度
2-8°C
SMILES字符串
F[P-](F)(F)(F)(F)F.CC(C)C[C@@H](CO)[N+]1=CN(CC1)c2c(C)cc(C)cc2C
InChI
1S/C18H29N2O.F6P/c1-13(2)8-17(11-21)19-6-7-20(12-19)18-15(4)9-14(3)10-16(18)5;1-7(2,3,4,5)6/h9-10,12-13,17,21H,6-8,11H2,1-5H3;/q+1;-1/t17-;/m0./s1
InChI key
NTQWYGMQOMHOQG-LMOVPXPDSA-N
应用
与铜共同用于格氏共轭加成生成烯酮的手性 NHC
警示用语：
Danger
危险声明
危险分类
Skin Corr. 1B
储存分类代码
8B - Non-combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
此项目有
David Martin et al.
Journal of the American Chemical Society, 128(26), 8416-8417 (2006-06-29)
The copper-catalyzed asymmetric conjugate addition of Grignard reagents to trisubstituted cyclic enones affords enantioenriched all-carbon quaternary centers with up to 96% ee. The chiral ligand is a diaminocarbene, directly generated in situ. The combination of Grignard reagent and diaminocarbene is
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