700770
(R)-SIPHOS-PE
97%
别名:
(11aR)-(+)-10,11,12,13-四氢茚并[7,1-de:1′, 7′-fg][1,3,2]二氧磷-5-双[(R)-1-苯乙基]胺, N-二[(R)-1-苯乙基]-[(R)-1,1′-螺二氢茚-7,7′-二基]亚磷酰胺
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关于此项目
经验公式（希尔记法）:
C33H32NO2P
化学文摘社编号:
分子量:
505.59
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
产品名称
(R)-SIPHOS-PE, 97%
InChI
1S/C33H32NO2P/c1-23(25-11-5-3-6-12-25)34(24(2)26-13-7-4-8-14-26)37-35-29-17-9-15-27-19-21-33(31(27)29)22-20-28-16-10-18-30(36-37)32(28)33/h3-18,23-24H,19-22H2,1-2H3/t23-,24-,33?/m1/s1
InChI key
ZXLQLIDJAURBDD-HRPAVAKOSA-N
assay
97%
form
powder
optical activity
[α]22/D +337°, c = 1 in chloroform
mp
90-96 °C
storage temp.
−20°C
Application
(R)-SIPHOS-PE can be used as:
- A catalyst in the preparation of tricyclic alkaloid (+)-aphanorphine via asymmetric carboamination and Friedel−Crafts reaction.
- A ligand in the synthesis of chiral ketones via hydroacylation of olefins using salicylaldehyde derivatives.
- A ligand in the enantioselective synthesis of substituted pyrrolidine derivatives via Pd-catalyzed alkene aminoarylation reactions.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Enantioconvergent synthesis of (+)-aphanorphine via asymmetric Pd-catalyzed alkene carboamination
Mai DN, et al.
Organic Letters, 13(11), 2932-2935 (2011)
Recent developments in palladium-catalyzed alkene aminoarylation reactions for the synthesis of nitrogen heterocycles
Schultz DM and Wolfe JP
Synthesis, 44(03), 351-361 (2012)
Regio-and enantioselective intermolecular hydroacylation: Substrate-directed addition of salicylaldehydes to homoallylic sulfides
Coulter MM, et al.
Journal of the American Chemical Society, 132(46), 16330-16333 (2010)
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