704830
5-溴-2-(三丁基甲锡烷基)吡啶
97% (H-NMR)
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关于此项目
经验公式（希尔记法）:
C17H30BrNSn
化学文摘社编号:
分子量:
447.04
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
产品名称
5-溴-2-(三丁基甲锡烷基)吡啶, 97% (H-NMR)
InChI
1S/C5H3BrN.3C4H9.Sn/c6-5-2-1-3-7-4-5;3*1-3-4-2;/h1-2,4H;3*1,3-4H2,2H3;
SMILES string
CCCC[Sn](CCCC)(CCCC)c1ccc(Br)cn1
InChI key
ZQJRPQMEYHJPJK-UHFFFAOYSA-N
assay
97% (H-NMR)
form
liquid
refractive index
n20/D 1.535
bp
140-145 °C
density
1.317 g/mL at 25 °C
functional group
bromo
Application
5-Bromo-2-(tributylstannyl)pyridine can be used in the synthesis of:
- 1,10-Phenanthroline based ditopic ligand, which is used to prepare bistable metallic rotaxanes.
- Donor-acceptor type isomeric platinum(II) complexes exhibiting excellent optoelectronic properties for OLED applications.
- Pt(II) polymetallayne derived orange phosphorescent polymers applicable in phosphorescent OLEDs (PHOLEDs).
signalword
Danger
Hazard Classifications
Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 1
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Enhancing the electroluminescence performances of novel platinum (ii) polymetallayne-based phosphorescent polymers through employing functionalized Ir III phosphorescent units and facilitating triplet energy transfer
Huang Z, et al.
Royal Society of Chemistry Advances, 5(16), 12100-12110 (2015)
Achieving NIR emission for donor-acceptor type platinum (II) complexes by adjusting coordination position with isomeric ligands
Zhang Y, et al.
Inorganic Chemistry, 57(22), 14208-14217 (2018)
Synthesis of a novel ditopic ligand incorporating directly bonded 1, 10-phenanthroline and 2, 2': 6', 2 ?-terpyridine units.
Gavi?a P and Tatay S.
Tetrahedron Letters, 47(20), 3471-3473 (2006)
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