704938
N-苄基-2-溴-N-苯基丙酰胺
97%
别名:
2-溴-N-苯基-N-(苯基甲基)丙酰胺, N-苄基-2-溴-丙酰苯胺
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关于此项目
经验公式（希尔记法）:
C16H16BrNO
化学文摘社编号:
分子量:
318.21
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
97%
Form:
solid
InChI
1S/C16H16BrNO/c1-13(17)16(19)18(15-10-6-3-7-11-15)12-14-8-4-2-5-9-14/h2-11,13H,12H2,1H3
SMILES string
CC(Br)C(=O)N(Cc1ccccc1)c2ccccc2
InChI key
SVPMVGLFGUEUOK-UHFFFAOYSA-N
assay
97%
form
solid
mp
75-80 °C
functional group
amide, bromo, phenyl
Application
用于双唑啉型吡啶-镍络合物催化的不对称根岸偶联反应。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Christian Fischer et al.
Journal of the American Chemical Society, 127(13), 4594-4595 (2005-03-31)
A Ni/Pybox catalyst achieves the asymmetric cross-coupling of secondary alpha-bromo amides with organozinc reagents. The process tolerates a variety of functional groups and affords the desired product in good yield and in high enantiomeric excess.
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