706000
氟三（三苯基膦）铜（I）
95% (by HMR)
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关于此项目
经验公式（希尔记法）:
C54H45CuFP3
化学文摘社编号:
分子量:
869.40
UNSPSC Code:
12352300
PubChem Substance ID:
MDL number:
InChI
1S/3C18H15P.Cu.FH/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;;1H/q;;;+1;/p-1
SMILES string
F[Cu].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
InChI key
OKJARODAQSGFQE-UHFFFAOYSA-M
assay
95% (by HMR)
form
solid
reaction suitability
reagent type: catalyst
core: copper
mp
144-157 °C
General description
络合物产品可能含多达 9%（质量分数）的乙醇。
Application
用于不对称羟醛反应的络合物
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
新产品
此项目有
Kounosuke Oisaki et al.
Journal of the American Chemical Society, 128(22), 7164-7165 (2006-06-01)
An enantioselective aldol reaction between ketones and ketene silyl acetals is described using CuF-chiral phosphine as a catalyst. The key for high enantioselectivity was the development of a novel ligand derived from Taniaphos combined with the unique accelerative effect of
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