706671
(4S,5S)-2-烯丙基-2-氯-3,4-二甲基-5-苯基-1-氧杂-3-氮杂-2-硅杂环戊烷
别名:
(1S,2S)-伪麻黄碱烯丙基氯硅烷, (4S,5S)-2-氯-3,4-二甲基-5-苯基-2-(2-丙烯基)-1-氧杂-3-氮杂-2-硅杂环戊烷, (4S,5S)-2-烯丙基-2-氯-3,4-二甲基-5-苯基-1,3,2-氧氮杂硅杂环戊烷
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关于此项目
经验公式（希尔记法）:
C13H18ClNOSi
化学文摘社编号:
分子量:
267.83
UNSPSC Code:
12352103
PubChem Substance ID:
MDL number:
InChI
1S/C13H18ClNOSi/c1-4-10-17(14)15(3)11(2)13(16-17)12-8-6-5-7-9-12/h4-9,11,13H,1,10H2,2-3H3/t11-,13+,17?/m0/s1
SMILES string
C[C@H]1[C@@H](O[Si](Cl)(CC=C)N1C)c2ccccc2
InChI key
XHCRAANIMMYPDV-APBZJUGRSA-N
form
liquid
optical activity
[α]20/D 72.5°, c = 0.6 in ethanol (200 proof)
refractive index
n20/D 1.517
bp
120 °C/5 mmHg
density
1.095 g/mL at 25 °C
General description
该产品为非对映异构体混合物。
Application
用于醛的对映选择性烯丙基化反应的试剂。
Leighton′s Strained Silacycles: Powerful Enantioselective Allylation Reagents
- Practical, enantioselective allylation of acylhydrazones
- Enantioselective allylation of ketimines: synthesis of tertiary carbinamines
Legal Information
美国专利 No.7,534,905
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3 - Water-react 2
target_organs
Respiratory system
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
100.4 °F
flash_point_c
38 °C
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
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James W A Kinnaird et al.
Journal of the American Chemical Society, 124(27), 7920-7921 (2002-07-04)
A new reagent for the enantioselective allylation of aliphatic aldehydes has been developed. The reagent is easily prepared in a single step from commercially available materials and may be stored without significant decomposition. The reactivity of the reagent is attributed
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