708275
1,3-双-(2,6-二异丙基苯基)-[1,3,2]二氮杂磷啶 2-氧化物
97%
别名:
1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3,2-diazaphospholidine 2-oxide
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关于此项目
经验公式（希尔记法）:
C26H39N2OP
化学文摘社编号:
分子量:
426.57
UNSPSC Code:
12352005
PubChem Substance ID:
MDL number:
InChI
1S/C26H39N2OP/c1-17(2)21-11-9-12-22(18(3)4)25(21)27-15-16-28(30(27)29)26-23(19(5)6)13-10-14-24(26)20(7)8/h9-14,17-20,30H,15-16H2,1-8H3
SMILES string
CC(C)c1cccc(C(C)C)c1N2CCN(c3c(cccc3C(C)C)C(C)C)[PH]2=O
InChI key
SQYNIVDXVZPMLW-UHFFFAOYSA-N
assay
97%
form
solid
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
mp
205-210 °C
functional group
phosphine
Application
与钌共同用于芳烃与酚脱水直接芳基化的配体
Reactnat for synthesis of air-stable palladium HASPO complexes
Catalyst for:
Catalyst for:
- Dehydrative direct arylations of arenes
- Aryl-(hetero)aryl coupling by activation of C-Cl and C-F bonds
存储类别
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Lutz Ackermann et al.
Organic letters, 10(21), 5043-5045 (2008-10-16)
Phenols can be employed as proelectrophiles in operationally simple ruthenium-catalyzed dehydrative direct arylations, proceeding through chemo- and regioselective functionalizations of C-H and C-OH bonds.
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