708518
1,3-双(二苯基膦甲基)苯
powder
别名:
α,α′-Bis(diphenylphosphino)-m-xylene, [1,3-Phenylenebis(methylene)]bis[diphenyl]phosphine
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选择尺寸
关于此项目
经验公式（希尔记法）:
C32H28P2
化学文摘社编号:
分子量:
474.51
UNSPSC Code:
12352002
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
1,3-双(二苯基膦甲基)苯,
SMILES string
C(P(c1ccccc1)c2ccccc2)c3cccc(CP(c4ccccc4)c5ccccc5)c3
InChI
1S/C32H28P2/c1-5-16-29(17-6-1)33(30-18-7-2-8-19-30)25-27-14-13-15-28(24-27)26-34(31-20-9-3-10-21-31)32-22-11-4-12-23-32/h1-24H,25-26H2
InChI key
QLSOZHFOFHARBJ-UHFFFAOYSA-N
form
powder
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
mp
50-55 °C
functional group
phosphine
Application
Reactant for:
- Cyclometalation of pincer ligands
- Insertion of carbon dioxide into (PCP)PDII-Me Bonds
- Synthesis of iridium complexes containing bidentate phosphine ligands
- Transcyclometalation processes
- Synthesis of vinylidene and carbyne complexes
hcodes
pcodes
Hazard Classifications
Aquatic Chronic 4
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
>230.0 °F
flash_point_c
> 110 °C
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