主要文件

查看所有文档

708682

RuCl[(R,R)-TsDPEN](均三甲苯)

Name: RuCl[(<I>R</I>,<I>R</I>)-TsDPEN](均三甲苯)
Brand: ALDRICH

90%

别名:

[N-[(1R,2R)-2-(氨基-κN)-1,2-二苯乙基]-4-甲基苯磺酰胺合-κN]氯[(1,2,3,4,5,6-η)-1,3,5-三甲苯]-钌

登录查看组织和合同定价。

选择尺寸

变更视图

关于此项目

经验公式（希尔记法）:

C₃₀H₃₃ClN₂O₂RuS

化学文摘社编号:

174813-82-2

分子量:

622.18

NACRES:

NA.22

PubChem Substance ID:

329762817

UNSPSC Code:

12352116

MDL number:

MFCD12545951

技术服务

需要帮助？我们经验丰富的科学家团队随时乐意为您服务。

让我们为您提供帮助

属性

Quality Level

100

assay

90%

form

solid

mp

241-249 °C

functional group

amine, phenyl

storage temp.

2-8°C

SMILES string

Cc1cc(C)cc(C)c1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@@H]([C@H](N)c3ccccc3)c4ccccc4

InChI

1S/C21H21N2O2S.C9H12.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-7-4-8(2)6-9(3)5-7;;/h2-15,20-21H,22H2,1H3;4-6H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m1.../s1

InChI key

XBNBOGZUDCYNOJ-AGEKDOICSA-M

说明

Application

RuCl[(R,R)-TsDPEN](mesitylene) may be used as a catalyst to synthesize:

(2R,3S)-4-Benzyl-2-(hydroxyphenylmethyl)morpholin-3-one from racemic N-benzyl-2-benzoyl-3-morpholinone via dynamic kinetic resolution-based asymmetric transfer hydrogenation (ATH).
Chiral nonracemic δ-phenylseleno alcohols from δ-phenylseleno ketones via catalytic ATH reaction.

Takasago Ligands and Complexes for Asymmetric Reactions

Legal Information

与 Takasago 合作销售，仅用于研究目的。WO9720789

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

没有发现合适的版本？

如果您需要特殊版本，可通过批号或批次号查找具体证书。

搜索COA

已有该产品？

在文件库中查找您最近购买产品的文档。

访问文档库

商品

Takasago Ligands

Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago

Dynamic Kinetic Resolution-Based Asymmetric Transfer Hydrogenation of 2-Benzoylmorpholinones and Its Use in Concise Stereoselective Synthesis of All Four Stereoisomers of the Antidepressant Reboxetine.

Son SM and Lee HK.

The Journal of Organic Chemistry, 78(17), 8396-8404 (2013)

Stereoselective Synthesis of Substituted Tetrahydropyrans and Isochromans by Cyclization of Phenylseleno Alcohols.

Temperini A, et al.

The Journal of Organic Chemistry, 80(16), 8102-8112 (2015)

全球贸易项目编号

货号	GTIN
708682-500MG	04061832843087