708682
RuCl[(R,R)-TsDPEN](均三甲苯)
90%
别名:
[N-[(1R,2R)-2-(氨基-κN)-1,2-二苯乙基]-4-甲基苯磺酰胺合-κN]氯[(1,2,3,4,5,6-η)-1,3,5-三甲苯]-钌
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关于此项目
经验公式（希尔记法）:
C30H33ClN2O2RuS
化学文摘社编号:
分子量:
622.18
MDL编号:
UNSPSC代码:
12352116
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
90%
表单
solid
mp
241-249 °C
官能团
amine
phenyl
储存温度
2-8°C
SMILES字符串
Cc1cc(C)cc(C)c1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@@H]([C@H](N)c3ccccc3)c4ccccc4
InChI
1S/C21H21N2O2S.C9H12.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-7-4-8(2)6-9(3)5-7;;/h2-15,20-21H,22H2,1H3;4-6H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m1.../s1
InChI key
XBNBOGZUDCYNOJ-AGEKDOICSA-M
应用
RuCl[(R,R)-TsDPEN](mesitylene) may be used as a catalyst to synthesize:
- (2R,3S)-4-Benzyl-2-(hydroxyphenylmethyl)morpholin-3-one from racemic N-benzyl-2-benzoyl-3-morpholinone via dynamic kinetic resolution-based asymmetric transfer hydrogenation (ATH).
- Chiral nonracemic δ-phenylseleno alcohols from δ-phenylseleno ketones via catalytic ATH reaction.
法律信息
与 Takasago 合作销售，仅用于研究目的。WO9720789
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Stereoselective Synthesis of Substituted Tetrahydropyrans and Isochromans by Cyclization of Phenylseleno Alcohols.
Temperini A, et al.
The Journal of Organic Chemistry, 80(16), 8102-8112 (2015)
Dynamic Kinetic Resolution-Based Asymmetric Transfer Hydrogenation of 2-Benzoylmorpholinones and Its Use in Concise Stereoselective Synthesis of All Four Stereoisomers of the Antidepressant Reboxetine.
Son SM and Lee HK.
The Journal of Organic Chemistry, 78(17), 8396-8404 (2013)
商品
Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago
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