712892
(S)-(−)-2-(二苄氨基)丙醛
97%
别名:
(S)-2-(Dibenzylamino)propanal, N,N-Dibenzyl-L-alaninal
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关于此项目
经验公式（希尔记法）:
C17H19NO
化学文摘社编号:
分子量:
253.34
UNSPSC Code:
12352114
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4293933
产品名称
(S)-(−)-2-(二苄氨基)丙醛, 97%
InChI
1S/C17H19NO/c1-15(14-19)18(12-16-8-4-2-5-9-16)13-17-10-6-3-7-11-17/h2-11,14-15H,12-13H2,1H3/t15-/m0/s1
SMILES string
C[C@@H](C=O)N(Cc1ccccc1)Cc2ccccc2
InChI key
GFYXFRCVQSKSDO-HNNXBMFYSA-N
assay
96.5-103.5% (NT)
97%
form
crystals
optical activity
[α]/D -36.0±2.0°, c = 1 in ethanol
functional group
aldehyde
amine
phenyl
storage temp.
2-8°C
Application
(S)-(-)-2-(Dibenzylamino)propionaldehyde can be employed as a building block for the preparation of:
- Linezolid dipeptide derivatives and 3-oxazolidin-2-one analogs.
- (2R,3S)-3-Dibenzylamine-1-nitrobutan-2-ol by reacting with bromonitromethane via nitro-aldol reaction using SmI2 as a catalyst.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Skin Sens. 1
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
法规信息
新产品
此项目有
Efficient nitro-aldol reaction using SmI2: A new route to nitro alcohols under very mild conditions
Concellon J, et al.
The Journal of Organic Chemistry, 71(20), 7919-7922 (2006)
Antibacterial activity of new oxazolidin-2-one analogues in methicillin-resistant Staphylococcus aureus strains
Cordova-Guerrero, et al.
International Journal of Molecular Sciences, 15(4), 5277-5291 (2014)
Design, synthesis and evaluation of the antibacterial activity of new Linezolid dipeptide-type analogues
Garcia-Olaiz GD, et al.
Bioorganic Chemistry, 95, 103483-103483 (2020)
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