713368
(S)-α-(苯甲基)-1-吡咯烷乙胺
96%
别名:
(S)-2-苯基-1-吡咯烷-1-基甲基-乙胺
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关于此项目
经验公式（希尔记法）:
C13H20N2
化学文摘社编号:
分子量:
204.31
Beilstein:
10160096
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
方案
≥95.5% (GC)
95.5-104.5% (NT)
96%
表单
liquid
旋光性
[α]/D +5.0±1.0°, c = 1 in methanol
官能团
amine
phenyl
储存温度
2-8°C
SMILES字符串
N[C@H](CN1CCCC1)Cc2ccccc2
InChI
1S/C13H20N2/c14-13(11-15-8-4-5-9-15)10-12-6-2-1-3-7-12/h1-3,6-7,13H,4-5,8-11,14H2/t13-/m0/s1
InChI key
YDLCAQYNXGDYTM-ZDUSSCGKSA-N
应用
(S)-α-(Phenylmethyl)-1-pyrrolidinethanamine can be used as an organocatalyst:
- In the Michael addition reaction of α-substituted vinyl ketones with malononitriles.
- In the aldol reactions of α-hydroxyketones with substituted aldehydes.
- In the asymmetric conjugate addition of vinyl ketones to azoles.
警示用语：
Danger
危险声明
危险分类
Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Chiral Primary- Tertiary Diamine Catalysts Derived From Natural Amino Acids for syn-Aldol Reactions of Hydroxy Ketones
Li J, et al.
The Journal of Organic Chemistry, 74(4), 1747-1750 (2009)
Chiral primary amine catalyzed asymmetric Michael addition of malononitrile to α-substituted vinyl ketone
Fu, Niankai and Zhang, Long and Luo, Sanzhong
Organic Letters, 17(2), 382-385 (2015)
Chiral primary amine catalysed asymmetric conjugate addition of azoles to α-substituted vinyl ketones
Fu N, et al.
Organic Chemistry Frontiers : An International Journal of Organic Chemistry / Royal Society of Chemistry, 1(1), 68-72 (2014)
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