715964
(1S,2S)-N,N′-二甲基-1,2-二苯基-1,2-乙二胺
97%
别名:
(1S,2S)-N,N′-二甲基-1,2-二苯基乙烷-1,2-二胺
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选择尺寸
关于此项目
经验公式（希尔记法）:
C16H20N2
化学文摘社编号:
分子量:
240.34
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352116
MDL number:
Assay:
97%
Form:
solid
InChI
1S/C16H20N2/c1-17-15(13-9-5-3-6-10-13)16(18-2)14-11-7-4-8-12-14/h3-12,15-18H,1-2H3/t15-,16-/m0/s1
SMILES string
CN[C@H]([C@@H](NC)c1ccccc1)c2ccccc2
InChI key
BTHYVQUNQHWNLS-HOTGVXAUSA-N
assay
97%
form
solid
optical activity
[α]22/D −17.0°, c = 0.5 in chloroform
mp
48-53 °C
functional group
amine, phenyl
Quality Level
Application
(1S,2S)-N,N′-Dimethyl-1,2-diphenyl-1,2-ethylenediamine can be used as:
- A precursor for the synthesis of chiral imidazolinium salts, which are used as catalysts for aza Diels−Alder reaction and as shift reagents for potassium salt of Mosher′s acid.
- A ligand in the preparation of 2,3-dihydrobenzofurans and indanes by reacting alkyl halides with alkyl electrophiles using nickel/diamine catalyst.
- A ligand in the synthesis of carbamates, sulfonamides, and sulfones through alkyl-alkyl Suzuki reaction using Ni catalyst.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Catalytic enantioselective cyclization/cross-coupling with alkyl electrophiles
Cong H and Fu GC
Journal of the American Chemical Society, 136(10), 3788-3791 (2014)
New directing groups for metal-catalyzed asymmetric carbon-carbon bond-forming processes: stereoconvergent alkyl-alkyl Suzuki cross-couplings of unactivated electrophiles
Wilsily A, et al.
Journal of the American Chemical Society, 134(13), 5794-5797 (2012)
The preparation of new enantiopure imidazolinium salts and their evaluation as catalysts and shift reagents
Jurcik V and Wilhelm R
Tetrahedron Asymmetry, 17(5), 801-810 (2006)
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