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Merck
CN

71620

氢化钠

powder (moistened with oil), 55-65% (gas-volumetric)

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线性分子式:
NaH
化学文摘社编号:
分子量:
24.00
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
26111700
MDL number:
Form:
powder (moistened with oil)
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InChI

1S/Na.H

SMILES string

[Na]

InChI key

MPMYQQHEHYDOCL-UHFFFAOYSA-N

form

powder (moistened with oil)

reaction suitability

reagent type: reductant

concentration

55-65% (gas-volumetric)

mp

800 °C (dec.) (lit.)

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General description

通过在升高的温度下使金属钠与氢气反应,可以容易地形成氢化钠。NaH 对水分和空气非常敏感。它可以在趋向氧化物的脱嵌中用作强还原剂。晶体结构由具有间隙氢化物离子的立方 Na 构成。氢化钠表现出高重量储氢能力。

Application

直接嵌入 C60 可得到超导材料 (NaH)4C60

Packaging

塑料袋封装,可在 45-60°C 下溶于碳氢化合物、THF 和二恶烷中。

pictograms

FlameCorrosion

signalword

Danger

hcodes

Hazard Classifications

Met. Corr. 1 - Water-react 1

存储类别

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

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分析证书(COA)

Lot/Batch Number

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Sodium hydride as a powerful reducing agent for topotactic oxide deintercalation: Synthesis and characterization of the nickel (I) oxide LaNiO2.
Hayward MA, et al.
Journal of the American Chemical Society, 121(38), 8843-8854 (1999)
Hiroshi Fukasawa et al.
ACS chemical neuroscience, 5(7), 525-532 (2014-04-18)
Neuropathic pain is a chronic condition resulting from neuronal damage. Pregabalin, the (S)-isomer of 3-isobutyl-γ-aminobutyric acid (GABA), is widely used to treat neuropathic pain, despite the occurrence of central nervous system (CNS)-related side effects such as dizziness and somnolence. Here
Nanoarchitecture of Protective Coatings for Air Sensitive Metal Hydrides
Dobbins T
Material Matters, 2(2), 19-19 (2007)
Formation of Crystalline Sodium Hydride Nanoparticles Encapsulated Within an Amorphous Framework.
Sartbaeva A, et al.
Journal of Cluster Science, 21(3), 543-549 null
Shuo Xing et al.
Organic & biomolecular chemistry, 13(5), 1515-1520 (2014-12-06)
A novel synthetic route leading to N-glycolyl muramyl dipeptide (MDP), a bacterial glycopeptide of particular interest in studies of nucleotide-binding oligomerization domain-containing protein 2 (NOD2), is described. The synthetic strategy hinges on the alkylation of benzylidene-protected glucal with 2-bromopropionic acid

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