723185
1,1,1-三(2-溴异丁酰氧甲基)乙烷
97%
别名:
3f-BiB, 三官能引发剂
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关于此项目
经验公式（希尔记法）:
C17H27Br3O6
化学文摘社编号:
分子量:
567.10
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12162002
MDL number:
InChI
1S/C17H27Br3O6/c1-14(2,18)11(21)24-8-17(7,9-25-12(22)15(3,4)19)10-26-13(23)16(5,6)20/h8-10H2,1-7H3
SMILES string
CC(C)(Br)C(=O)OCC(C)(COC(=O)C(C)(C)Br)COC(=O)C(C)(C)Br
InChI key
VLRDGSDXAISNJF-UHFFFAOYSA-N
assay
97%
form
powder
mp
54-60 °C
Application
Atom Transfer Radical Polymerization (ATRP) initiator for the creation of trifunctional polymers.
Polymerization will occur at three sites creating a three-arm star polymer.
Polymerization will occur at three sites creating a three-arm star polymer.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
nwg
flash_point_f
>230.0 °F - closed cup
flash_point_c
> 110 °C - closed cup
Coessens, V.; Pintauer, T.; Matyjaszewski, K.
Progress in Polymer Science, 36, 337-337 (2001)
Atom transfer radical polymerization.
K Matyjaszewski et al.
Chemical reviews, 101(9), 2921-2990 (2001-12-26)
"Green" atom transfer radical polymerization: from process design to preparation of well-defined environmentally friendly polymeric materials.
Nicolay V Tsarevsky et al.
Chemical reviews, 107(6), 2270-2299 (2007-05-29)
商品
ATRP is a successful method for precise polymer synthesis with controlled molecular weights and high chain end functionalities.
实验方案
Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.
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