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Merck
CN

726621

(R)-(+)-α-甲基苄胺

ChiPros®, produced by BASF, ≥99.0%

别名:

(R)-(+)-1-苯乙胺

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关于此项目

线性分子式:
C6H5CH(CH3)NH2
化学文摘社编号:
3886-69-9
分子量:
121.18
UNSPSC Code:
12352116
NACRES:
NA.22
PubChem Substance ID:
329764252
EC Number:
223-423-4
Beilstein/REAXYS Number:
2410916
MDL number:
MFCD00064405
Assay:
≥99.0% (GC), ≥99.0%
Form:
liquid

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InChI key

RQEUFEKYXDPUSK-SSDOTTSWSA-N

InChI

1S/C8H11N/c1-7(9)8-5-3-2-4-6-8/h2-7H,9H2,1H3/t7-/m1/s1

SMILES string

C[C@@H](N)c1ccccc1

vapor pressure

0.5 mmHg ( 20 °C)

description

Drug Control: Pszichotróp anyag / Psychotropic Substance (Hungary), 78/2022. (XII. 28.) BM rendelet.

assay

≥99.0% (GC), ≥99.0%

form

liquid

optical purity

enantiomeric excess: ≥98.0%

drug control

Pszichotróp anyag / Psychotropic Substance (Hungary), 78/2022. (XII. 28.) BM rendelet

refractive index

n20/D 1.526 (lit.)

bp

187-189 °C (lit.)

density

0.952 g/mL at 20 °C (lit.)

functional group

amine, phenyl

Quality Level

100

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相关类别

General description

(R)-(+)-α-Methylbenzylamine is a chiral amine.

Application

(R)-(+)-α-Methylbenzylamine may be used as a substrate to synthesize:
  • (S)-α-amino phosphonates
  • N-{(S)-[cyclohexan-(S)-2-ol]}-(R)-α-methylbenzyl amine and N-{(R)-[cyclohexan-(R)-2-ol]}-(R)-α-methylbenzyl amine
  • R-α-aminonitriles

Legal Information

ChiPros is a registered trademark of BASF SE

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

158.0 °F - closed cup

flash_point_c

70 °C - closed cup

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCBQ9373V
BCBM5250V
BCBG4718V
BCBC4052
BCBC4052V

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New enantiomerically pure aminoalcohols from (R)-a-methylbenzylamine and cyclohexene oxide.
Barbaro P, et al.
Tetrahedron Asymmetry, 7(3), 843-850 (1996)
Lithium perchlorate/diethylether catalyzed aminophosphonation of aldehydes.
Heydari A, et al.
Tetrahedron Letters, 39(37), 6729-6732 (1998)
ChiPros Chiral Amines
Aldrich Chemfiles, 11(1) null
Andrew M Kelly et al.
Nature protocols, 3(2), 215-219 (2008-02-16)
A three-component chiral derivatization protocol for determining the enantiopurity of chiral diols by (1)H NMR spectroscopic analysis is described here. The present approach involves the derivatization of 1,2- 1,3- and 1,4-diols with 2-formylphenylboronic acid and enantiopure alpha-methylbenzylamine. This method affords
Alejandra León et al.
Journal of natural products, 75(5), 859-864 (2012-05-12)
The enantiomeric lactams (-)-8, (+)-8, (+)-9, and (-)-9 were formed by the reaction of the dimeric phthalide rac-tokinolide B (rac-3) with (R)-(+)-α-methylbenzylamine and (S)-(-)-α-methylbenzylamine. The absolute configurations of compounds 8 and 9 were assigned by experimental and theoretically calculated electronic
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商品

ChiPros Chiral Amines

Chiral amines play an important role in stereoselective organic synthesis. They are used directly as resolving agents, building blocks, or chiral auxiliaries.

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