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Merck
CN

726621

(R)-(+)-α-甲基苄胺

ChiPros®, produced by BASF, ≥99.0%

别名:

(R)-(+)-1-苯乙胺

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关于此项目

线性分子式:
C6H5CH(CH3)NH2
化学文摘社编号:
3886-69-9
分子量:
121.18
UNSPSC Code:
12352116
NACRES:
NA.22
PubChem Substance ID:
329764252
EC Number:
223-423-4
Beilstein/REAXYS Number:
2410916
MDL number:
MFCD00064405

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产品名称

(R)-(+)-α-甲基苄胺, ChiPros®, produced by BASF, ≥99.0%

InChI key

RQEUFEKYXDPUSK-SSDOTTSWSA-N

InChI

1S/C8H11N/c1-7(9)8-5-3-2-4-6-8/h2-7H,9H2,1H3/t7-/m1/s1

SMILES string

C[C@@H](N)c1ccccc1

vapor pressure

0.5 mmHg ( 20 °C)

description

Drug Control: Pszichotróp anyag / Psychotropic Substance (Hungary), 78/2022. (XII. 28.) BM rendelet.

assay

≥99.0% (GC)
≥99.0%

form

liquid

optical purity

enantiomeric excess: ≥98.0%

drug control

Pszichotróp anyag / Psychotropic Substance (Hungary), 78/2022. (XII. 28.) BM rendelet

refractive index

n20/D 1.526 (lit.)

bp

187-189 °C (lit.)

density

0.952 g/mL at 20 °C (lit.)

functional group

amine
phenyl

Quality Level

100

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相关类别

Application

(R)-(+)-α-Methylbenzylamine may be used as a substrate to synthesize:
  • (S)-α-amino phosphonates
  • N-{(S)-[cyclohexan-(S)-2-ol]}-(R)-α-methylbenzyl amine and N-{(R)-[cyclohexan-(R)-2-ol]}-(R)-α-methylbenzyl amine
  • R-α-aminonitriles

General description

(R)-(+)-α-Methylbenzylamine is a chiral amine.

Legal Information

ChiPros is a registered trademark of BASF SE

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

158.0 °F - closed cup

flash_point_c

70 °C - closed cup

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCBQ9373V
BCBM5250V
BCBG4718V
BCBC4052
BCBC4052V

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New enantiomerically pure aminoalcohols from (R)-a-methylbenzylamine and cyclohexene oxide.
Barbaro P, et al.
Tetrahedron Asymmetry, 7(3), 843-850 (1996)
ChiPros Chiral Amines
Aldrich Chemfiles, 11(1) null
Lithium perchlorate/diethylether catalyzed aminophosphonation of aldehydes.
Heydari A, et al.
Tetrahedron Letters, 39(37), 6729-6732 (1998)
Karim Engelmark Cassimjee et al.
Organic & biomolecular chemistry, 10(28), 5466-5470 (2012-06-13)
For biocatalytic production of pharmaceutically important chiral amines the ω-transaminase enzymes have proven useful. Engineering of these enzymes has to some extent been accomplished by rational design, but mostly by directed evolution. By use of a homology model a key
Hyungdon Yun et al.
Bioscience, biotechnology, and biochemistry, 72(11), 3030-3033 (2008-11-11)
To produce (S)-alpha-methylbenzylamine (MBA) from acetophenone, recombinant Escherichia coli co-expressing omega-transaminase and acetolactate synthase was used as a whole-cell biocatalyst. The solvent-bridge reaction system increased the yield of the whole-cell reaction by 2.5-fold, and the inhibitory (S)-alpha-MBA produced in the
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商品

ChiPros Chiral Amines

Chiral amines play an important role in stereoselective organic synthesis. They are used directly as resolving agents, building blocks, or chiral auxiliaries.

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