727733
[2,6-双[(二-1-哌啶基膦)氨基]苯基]氯化钯(II)
≥98.0% (AT)
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关于此项目
经验公式（希尔记法）:
C26H45ClN6P2Pd
化学文摘社编号:
分子量:
645.50
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
方案
≥98.0% (AT)
表单
lumps
反应适用性
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
SMILES字符串
Cl[Pd]c1c(NP(N2CCCCC2)N3CCCCC3)cccc1NP(N4CCCCC4)N5CCCCC5
InChI
1S/C26H45N6P2.ClH.Pd/c1-5-16-29(17-6-1)33(30-18-7-2-8-19-30)27-25-14-13-15-26(24-25)28-34(31-20-9-3-10-21-31)32-22-11-4-12-23-32;;/h13-15,27-28H,1-12,16-23H2;1H;/q;;+1/p-1
InChI key
CSXBAGCRLXPPDX-UHFFFAOYSA-M
应用
Palladium catalyst for CC coupling reactions
- Performs Suzuki reactions at low loadings
- High activity at ppm levels for Heck reactions and Sonogashira couplings
包装
Bottomless glass bottle. Contents are inside inserted fused cone.
Jeanne L Bolliger et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 14(26), 7969-7977 (2008-07-12)
The aminophosphine-based pincer complexes [C6H3-2,6-(XP(piperidinyl)2)2Pd(Cl)] (X=NH 1; X=O 2) are readily prepared from cheap starting materials by sequential addition of 1,1',1''-phosphinetriyltripiperidine and 1,3-diaminobenzene or resorcinol to solutions of [Pd(cod)(Cl)2] (cod=cyclooctadiene) in toluene under N2 in "one pot". Compounds 1 and
Bolliger, J. L. and Frech,C. M.
Advanced Synthesis & Catalysis, 351, 891-902 (2009)
Bolliger, J. L. and Frech,C. M.,
Advanced Synthesis & Catalysis, 352, 1075-1080 (2010)
Short, facile, and high-yielding synthesis of extremely efficient pincer-type suzuki catalysts bearing aminophosphine substituents.
Jeanne L Bolliger et al.
Angewandte Chemie (International ed. in English), 46(34), 6514-6517 (2007-07-27)
Aminophosphine palladium pincer complexes for Suzuki and Heck reactions.
Bolliger, J. L., and Frech, C. M.
Chimia, 63, 23-23 (2009)
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